LiBOB电解液在石墨负极上的成膜性能 The capability of SEI film formed on the graphite in LiBOB based electrolytes.pdfVIP
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LiBOB电解液在石墨负极上的成膜性能 The capability of SEI film formed on the graphite in LiBOB based electrolytes
第36卷第5期 电 池 V01.36.No.5
2006薤10月 BATTERYBIMONTHLY 0ct..2006
LiBO
B电解液在石墨负极上的成膜性能
刘永欣,付延鲍,马晓华,杨清河
(复旦大学材料科学系,上海200433)
剂的LiBOB电解液的相容性进行了研究。石墨表面生成的SEI膜,不仅与电解液的组成和浓度有关,还与石墨的种类及结
构有关。在1.0mol/LLiBOB/PC电解液中,两种材料均能生成稳定的SEI膜;在0.5mol/LLiBOB/PC电解液中,MCMB
关键词:LiBOB;SEI膜;石墨;锂离子电池
中圈分类号:TM912.9文献标识码:A 文章编号:1001—1579(2006}05—0338—03
The ofSEIfilmformedonthe inLiBOBbased
capability graphite electrolytes
LIU Yan—bao,MAXiao—hua,YANG
Yong-xin,FU Qing—he
Materials
Science,Fudan 200433,China)
(Departmentof University,Shanghai
Abstract:The betweenlithium PCsolventandcarbon
his(oxalate)borate(LiBOB)based
compatibility electrolytescontaining
E-SLX50and Li—ion wasstudied and
MCMB)for
materials(syntheticgraphite battery bycyclicvohammetrycharge-dischargeey-
detests.TheformationofSEIfilmonthesurfaceof wasnot onthe andconcentrationofthe
graphite onlydependentcomposition
alsoonthekindsandstructuresoft11e SEIfdmcouldformonbothofthetwomaterials1.0
electrolyte,hut graphite.Stable using
mol/LLiBOB/PCas SEIfilmcouldform onMCMBwhen O.5mo]/LLiBOB/PCasthe
electrolyte.Stable only using electrolyte.
whileitcouldformonE-SLX50whenECWaSused∞co-solventinthe the ofECandLiBOB.
electrolyte.bycooperation
words:lithium
his(oxalate)borate(Li
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