LiFePO4-LiMn2O4混合正极材料对电池性能的影响 Effect of mixed LiFePO4-LiMn2O4 cathode material on the performance of batteries.pdfVIP
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LiFePO4-LiMn2O4混合正极材料对电池性能的影响 Effect of mixed LiFePO4-LiMn2O4 cathode material on the performance of batteries
高旭光,胡国荣, 彭忠东,万烨, 杜 柯,刘艳君
(中南大学冶金科学与工程学院,湖南长沙410083)
按照一定的质量比均匀混合用作锂离子电池正极材料。电池充放电测试表明电池的循环性能随着LiFePO。量的增加
二者混合试用可以有效地降低电极过程的电荷传递电阻。最后分析了循环性能提高的原因。
关键词:锂离子电池;正极材料;LiFeP04;LiMn204
912.9
中图分类号:TM 文献标识码:A 文章编号:1002—087
X(2007)11—0881—04
Effectmixed
of cathodematerial
LiFeP04.LiMn204
onthe ofbatteries
performance
GAO Ye,DUKe,LIU
Xu-guang,HUGuo—rong,PENGZhong—dong,WAN Yan-jun
fSchool Scienceand South Hunan
ofMetallurgicalEngineenng,CentralUniversity,Changsha410083,China)
Abstract:Thedifferent mixtureswithsub—micro—sized microwaveradiation
proportional LiFeP00./csynthesizedby
and solid-statemethodwereusedascathodematerialsfor¨thiumion
processingLiMn20apreparedby battery.The
resultsof testsshowthatthe becomesbetterwiththeincreaseof
charge-discharge cyclicperformance LiFePOdC.
The has and whentherateof and is3:2.The
battery cycliccapabilityhigherpowerdensity LiFeP04LiMn204
good
electrochemical indicatethat transfer be
impedancespectroscopy(EIS)measurementsresistance(闩d)can
charge
reducedwhen aremixedascathodematerial.Atlastthemechanismthatthe of
they improvementcyclic
wasdiscussed.
performance
words:¨thiumion
Key material;LiFeP04:LiMn204
battery;cathode
锂离子电池自上世纪90
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