Sr掺杂对Pt-CeO2C电催化甲醇性能的影响 Effect of Sr-doping for the electro-oxidation of methanol on Pt-CeO2C catalyst.pdfVIP
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Sr掺杂对Pt-CeO2C电催化甲醇性能的影响 Effect of Sr-doping for the electro-oxidation of methanol on Pt-CeO2C catalyst
Sr掺杂对Pt—Ce02/C电催化甲醇性能的影响
林茂财,余睛眷
(上海交通大学机械与动力工程学院燃料电池研究所,上海200240)
1 nm增大为0.5417
参数增大,当Sr掺杂量为5%时,Ce02的晶胞参数由0.541 nm。利用X射线衍射(XRD),透射
电镜(TEM)考察了催化剂的晶体结构和表面形貌,催化剂中Pl颗粒分布均匀。粒径大小为2—4nm。循环伏安测试
电氧化活性最高。
关键词:Sr掺杂;Ce02;电氧化;直接甲醇燃料电池
中图分类号:TM911.4文献标识码:A文章编号:1002—087
X(2009)06—0475—04
Effectof fortheelectro--oxidationofmethanolon
Sr--doping
Pt—CeO#C
catalyst
LIN
Mao·cai,YU
Qing—chun
ofFuel ofMechanical
(InstituteCell,School Engineering,ShanghaiJiaoTongUniversity,Shanghai200240,China)
were method.After were
Abstract:Sr-dopedCe02powderspreparedbyso-gel that,Pt-Cel一§rA一5/Ccatalysts
madereductionof saltswith structureof was XRD.
by platinum ethyleneglyc01.CrystalCe02samplesanalyzedby
An inthelattice of isobsewed.The ofthe was
Ce02 propedycatalyts
increasing parametersSr-doped physical
characterisedXRDand wasfoundthatthedistributionofthe was sizesofPt
narrow,the
by TEM.It catalyst particle
and were2~4nm.The indicatesthatthe formethanol
Ce02 voltammetry activity
cyclic testing electrocatalytic
electro—oxidationOf wasincreasedwhen was withSr.And the
Pt—Cel一S旧2—5/Ccatalysts Ce02doped especially
the
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