基于碳同位素组成的大气NMHCs 光化学寿命研究.PDF

中国环境科学 2010,30(7) ：980~984 China Environmental Science 基于碳同位素组成的大气 NMHCs 光化学寿命研究 彭 林 1*,任照芳 2,张会敏 1,牟 玲 2,施瑞良 2 (1.太原理工大学环境科学与工程学院, 山西 太原 030024 ；2. 太原理工大学矿业工程学院, 山西 太原 030024) 摘要：利用热解析-气相色谱-同位素质谱联用仪测定了兰州市冬季和夏季昼夜大气非甲烷烃(NMHCs) 的稳定碳同位素组成.结果表明,兰 州市冬季大气 NMHCs 的 δ13C 值为-30.5‰~-24.3‰,夏季为-31.9‰~-24.2%,受燃煤烟气排放的影响,冬季大气 NMHCs 的 δ13C 值明显大于 夏季;冬季大气 NMHCs 的 δ13C 值夜晚大于白天,夏季不同时间点 C 、C 化合物的同位素值相差不大,正己烷和正庚烷的 δ13C 值白天比夜 4 5 晚要高.利用“碳氢化合物同位素时钟”计算出正己烷和 1-丁烯在兰州市夏季大气中的平均光化学寿命分别约为 6d 和 25min. 关键词：非甲烷烃(NMHCs) ；稳定碳同位素组成；光化学寿命；大气 中图分类号：X8 文献标识码：A 文章编号：1000-6923(2010)07-0980-05 Photochemical age of atmospheric nonmethane hydrocarbons based on stable carbon isotopic composition. PENG Lin1* 2 1 2 2 , REN Zhao-fang , ZHANG Hui-min , MU Ling , SHI Rui-liang (1.College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China ；2.College of Mining Technology, Taiyuan University of Technology, Taiyuan 030024, China). China Environmental Science, 2010,30(7)：980~984 Abstract ：The diurnal stable carbon isotopic composition of nonmethane hydrocarbons (NMHCs) in winter and summer in Lanzhou was detected by thermal desorption-gas chromatography-isotope ratio mass chromatography (TD-GC-IR-MS) system. δ13C values of NMHCs were -30.5‰~-24.3‰ in winter, which was influenced by coal-combustion exhaust and higher than that in summer (-31.3‰~-24.2%). The δ13C values were generally higher at night than that in the daytime in winter, while the δ13C values of C and C NMHC compounds were similar in the different sampling time except higher 4 5 δ13C values of n-hexane and n-heptane in the daytime in summer. Based on the hydrocarbon isotopic clock, the average