纳米零价铁对溶液中铅镉铬砷去除性能研究.doc

纳米零价铁对溶液中铅镉铬砷的去除性能研究 张卫民a，李志勇a，李亦然a，王惠东a，廉欢a，陈程b （东华理工大学，a.水资源与环境工程学院，b.地球科学学院，南昌 330013） 摘要：通过液相还原法，采用KBH4还原Fe2+制备平均粒径4080 nm、比表面积19.713 4 m2/g有较好表面活性纳米零价铁NZVI)，NZVI在含初始浓度为100 mg/L的pH分别为2、7、12的溶液中进行去除试验。结果表明在pH=2pH=7的条件下NZVI对的去除效果较好，去除速率在前30较快；在pH=12条件下对的去除效果明显，去除速率在前40较快；不同pH条件下离子的去除率差异较大，这主要与各离子在不同pH条件下的存在形态有关。NVZI去除溶液中的，不仅效率高，而且绿色环保，不会对环境造成二次污染。 关键词：纳米零价铁NZVI)；比表面积；PbCr；Cd；As；去除率X703 文献标志码：A 文章编号：1007-7545（2017）08-0000-00 Study on Removal Performance of Lead, Cadmium, Chromium and Arsenic in Solution with Nanometer Zero-Valent Iron ZHANG Wei-mina, LI Zhi-yonga, LI Yi-rana, WANG Hui-donga, LIAN Huana, CHEN Chengb (a. School of Water Resources and Environmental Engineering, b. School of Earth Sciences, East China University of Technology, Nanchang 330013, China) Abstract：Nanoscale Zero-Valent Iron (NZVI) with average particle size of 40~80 nm, specific surface area of 19.713 4 m2/g, and better surface activity was synthesized in aqueous solutions by reduction of Fe2+ with KBH4. Experiment to remove Pb, Cr, Cd, and As in solution with initial concentration of 100 mg/L by NZVI under pH value of 2, 7, 12 respectively was carried out. The results show that removal efficiency of Pb, Cr and As is higher at pH=2 and pH=7, and removal rate is faster in the first 30 minutes. Removal efficiency of Cd is obvious at pH=12, and removal rate is faster in the first 40 minutes. Removal rate of ions under different pH conditions is different due to existence of ions. Removal of Pb, Cr, Cd, and As in solution with NVZI is not only efficient but also green without secondary pollution to environment. Key words：Nanoscale Zero-Valent IronNZVI); specific surface area; Pb; Cr; Cd; As; removal rate 随着经济与工业的发展，特别是重金属污染物事故性排放[1]，会含大量重金属的废水未经处理直接排入水体，造成严重污染。重金属在水体中不易被生物降解，具有生物富集和生物放大效应[23]。重金属污染已成为人类身体健康的主要威胁。 近年来，纳米零价铁(Nanoscale Zero-Valent Iron，NZVI)[4-5]作为水体污染修复剂得到了广泛应用。它既可以去除水体中的重金属污染物，又可以修复水体中的有机污染物。NZVI凭借其独特的性能以及对重金属离子有很好的去除能力，成为近年来处理水体污染物的研究热点[6-11]。 目前NZVI对含单一重金属离子溶液的去除试验有较多研究。本文用N