利用X射线近边吸收谱学方法研究蒙脱石在高温下吸附汞金属的行为.pdfVIP

29 Vol. 29, Supp. 2005 12 HIGH ENERGY PHYSICS AND NUCLEAR PHYSICS Dec., 2005 XANES Study of Hg Sorption Products on Montmorillonite at * High Temperatures CHU Wang-Sheng1,2 WU Zi-Yu1,2;1) LIU Wen-Han1 D. Malferrari3 M. F. Brigatti3 G. Cibin4 A. Marcelli4 1 (Deparment of Physics, University of Science and Technology of China, Hefei 230026, China) 2 (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, CAS, Beijing 100049, China) 3 (Dipartimento di Scienze della Terra, Universit`a di Modena e Reggio Emilia, L.go S. Eufemia 19, Italy) 4 (INFN-Laboratori Nazionali di Frascati, P.O.Box 13, 00044 Frascati, Italy) Abstract The Hg L -edge XANES spectra of montmorillonite treated with Hg(NO ) 0.01M aqueous 3 3 2 solution and the mixing solution of Hg(NO ) 0.01M aqueous solution and cysteine 0.01M aqueous solution 3 2 have been measured at several high temperatures. The adsorption and desorption of mercury in Hg-rich montmorillonite minerals and the effect of cysteine on the adsorption of mercury by this clay mineral were studied. Our analysis shows that mercury is six fold coordinated by water molecules and the oxygen atoms of montmorillonite surface without the amino acid introduction. Mercury atoms prefer to bond with