低合金耐候钢在两种典型环境下腐蚀行为.pdfVIP

低合金耐候钢在两种典型环境下的腐蚀行为 1 1 1 1 2 2 高新亮 付贵勤 邓志银 朱苗勇 曹 波 夏政海 （1. 东北大学材料与冶金学院，沈阳 110819 ； 2. 湖南华菱湘潭钢铁有限公司科技开发中心，湘潭 411101 ） 1 摘 要 通过干湿循环加速腐蚀实验并结合光学显微镜、SEM 和XRD 等方法，研究了低合金耐候钢在两种模拟大 气环境（海洋大气和工业大气）中的腐蚀行为和腐蚀产物的特征。实验结果表明：低合金钢在不同环境下的初期腐 蚀方式不同，在含Cl-环境下，珠光体和晶界被择优腐蚀；在含HSO32-环境下，实验钢趋于均匀腐蚀。 在工业大气 条件下，有利于α-FeOOH 生成。提高钢中合金元素Mn 和Ni 的含量，在模拟海洋大气条件下，初期加速钢的腐蚀 速率，后期提高钢的耐候性能；在模拟工业大气环境下，腐蚀初期和后期均有利于提高钢的耐蚀性能。 关键词 低合金耐候钢 腐蚀行为 初期腐蚀 腐蚀产物 Corrosion Behavior of Low Alloying Weathering Steels in Two Kinds of Typical Environments Gao Xinliang1 Fu Guiqin1 Deng Zhiyin1 Zhu Miaoyong1 Cao Bo2 Xia Zhenghai2 (1. School of Materials and Metallurgy, Northeastern University, Shenyang, 110819; 2. R and D Center, Xiangtan Iron and Steel Co., Ltd., Hunan Valin Group, Xiangtan, 411101) Abstract Alternate wet-dry cyclic accelerated corrosion tests together with optical microscopy, SEM and XRD were employed to investigate the corrosion behavior and corrosion products of two low alloying weathering steels in two kinds of typical environments (marine environment and industrial environment). The results show that the initial corrosion behavior of low alloying weathering steel is different in two kinds of typical environment. In the early stage of corrosion, pearlite phase and boundaries are easy to be corroded in environment containing chloride ions, while uniform corrosion appears in environment containing HSO32-. The formation of α-FeOOH is benefit in the simulated industrial environment. With increasing Ni and Mn content, the corrosion rate is accelerated at the early stage of corrosion in