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汪小兰有机化学第四版10-17章答案(Wang xiaolan organic chemistry fourth edition 10-17 answer)
Chapter 10: carboxylic acid and its derivatives
10.1 the naming of the system (please note if there is a common name) or write the structure
A. 2-methyl propionic acid b. o-hydroxybenzoic acid (salicylic acid) c. 2-butenic acid
3 d - bromine butyrate e. butyryl chloride f. g. butyl anhydride ethyl propionate h. Propyl acetate Propyl acetate
I. Benzamide j. Maleic acid
10.2 arrange the following compounds in an acidic order:
A. CH3CH2CHBrCO2H b. Ch3ch2h c. Ch3ch2ch2h 2h
D. Ch3ch2ch2ch2ch2ch2oh. C6H5OH
Answer: acidic sort g a b c f e h d
10.3 write the main products of the following reactions
The answer:
10.4 identify the following groups of compounds with simple chemical methods:
The answer:
A. KmnO4 b. FeCl3 c. Br2 or KmnO4 d. FeCl3, 2, 4-dinitrophenylhydrazine or I2 / NaOH
10.5 complete the following transformation:
The answer:
10.6 how to separate the mixture of hexanol, hexylic acid and methylphenol into a variety of pure components?
The answer:
10.7 write various isomers of unsaturated dicarboxylic acids with molecular formula C5H6O4. If there is a geometric isomerism, with Z, E, and points out which is prone to anhydride.
The answer:
(Z) anhydride (E) is not easy to become anhydride (E)
10.8 compound A, the molecular formula C4H6O4, after heating, the molecular formula is C4H4O3 B, and the formula of A and excess methanol and A small amount of sulfuric acid are obtained as C6H10O4 C. B and the excess methanol also get C. A and LiAlH4 have the molecular formula C4H10O2 D. Write the structure of A, B, C, D and their reciprocal transformation.
The answer:
Chapter 11 replaces the acid
11.1 write the structure or name of the following compounds.
M. n.
The answer:
M. 3 -- chlorobutyric acid (3 -- Chlorobutanoic acid) n.4 -- oxopentanoic acid (4 - oxopentanoic acid)
The following groups of compounds were identified by a simple chemical method.
B. CH3CH2CH2COCH3 CH3COCH2COCH3
The answ
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