以铁氧磁体触媒焚化BTEX之研究 - 国立高雄应用科技大学化学工程与 .DOC

中文摘要 苯(benzene)、甲苯(toluene)、乙苯(ethylbenzene)及二甲苯(xylenes)(合稱BTEX) 是典型的揮發性有機物(Volatile Organic Compounds, VOCs)，其所造成的空氣污染也一直為人所關注。 鐵氧磁體程序（Ferrite Process, FP）處理重金屬廢水所產生的污泥已被證實具有催化的能力。本研究使用FP合成七種鐵氧磁體觸媒（Cu-ferrite、Mn-ferrite、Ni-ferrite、Zn-ferrite、Cr-ferrite Co-ferrite、Pure-ferrite），藉以探討其應用於焚化BTEX的可行性。實驗結果顯示Cu-ferrite與Mn-ferrite均有很好的催化能力，並且以活性金屬和鐵的比例（M/Fe）為1/2.5者有最佳之效果。以Cu-ferrite（M/F＝1/2.5）進行焚化時，在流量1 NL/min、BTEX入口濃度1500 ppm下，達到95％去除率所需的溫度，分別為苯294 ℃、甲苯315 ℃、乙苯301 ℃、二甲苯320 ℃。相同條件下若改用Mn-ferrite（M/F＝1/2.5）進行焚化，則去除率達95％所需的溫度分別為苯299 ℃、甲苯285 ℃、乙苯270 ℃、二甲苯272 ℃。此外，經由改變觸媒焚化的操作參數，發現去除率隨著BTEX入口濃度以及進氣流量的增加而下降，此一現象在較低操作溫度時尤其明顯。 使用前後之鐵氧磁體觸媒以X光繞射儀鑑定發現均為尖晶石結構，焚化操作並未造成晶相之改變。由掃描式電子顯微鏡觀察得知晶體粒徑介於50~100 nm之間。BET比表面積分析的結果顯示各種鐵氧磁體觸媒之比表面積都在30 m2/g左右。 英文摘要 Benzene, toluene, ethylbenzene, and xylenes (denoted by BTEX) are the typical volatile organic compounds（VOCs）. Their impact to the air pollution is always concerned by human being. The sludge, generated from treatment of heavy metal wastewater by Ferrite Process, has been proven with the ability of catalysis. This study investigated the feasibility of incineration for BTEX over seven kinds of ferrite catalysts (Cu-ferrite, Mn-ferrite, Ni-ferrite, Zn-ferrite, Cr-ferrite Co-ferrite, and Pure-ferrite). Results show that both Cu-ferrite and Mn-ferrite have great catalytic ability, especially under the M/F ratio is 1/2.5. In incineration of BTEX over Cu-ferrite catalyst（M/F＝1/2.5）, under the conditions of flow rate 1 NL/min, BTEX inlet concentration 1500 ppm, the demand temperature for 95 % removal is 294 oC (Benzene), 315 oC (toluene), 301 oC (ethylbenzene), and 320 oC (xylenes), respectively. With the same conditions, the demand temperature for 95 % removal is 299 oC (Benzene), 285 oC (toluene), 270 oC (ethylbenzene), and 272 oC (xylenes), respectively when using the Mn-ferrite catalyst（M/F＝1/2.5）. It was also found that the removal efficiency decrease with the increasing of BTEX inlet concentration and flow rate. This phenomenom occur appare