分析化学答案3（Analytical chemistry answer 3）.docVIP

分析化学答案3（Analytical chemistry answer 3） The third chapter complexometric titration Questions 1, according to the complex nature of metal ions, which of the following complex is colored? What is the color? Cu2+- 3d94s0 has paired ethylenediamine colored D Zn2+- 3d104s0 all d pairs of ethylenediamine colorless electronic TiOY2- 3d04s0 all pairs D colorless TiY- 3d14s0 D nonferrous unpaired electron FeY2- 3d54s0 D nonferrous unpaired electron FeY- 3d54s0 D nonferrous unpaired electron 2, H2O2 can form three complex TiO and TiOY (H2O2) Y, but it makes TiOY the conditional stability constant increase or decrease? Why? Answer:. Due to the formation of TiO (H2O2) Y, so that the solution of [TiOY] is reduced to TiOY generation balance moving direction, has quite a side reaction to generate TiOY alpha TiOY1 LgK TiOY=lgKTiOY-lg, alpha Y-lg alpha TiOY+lg alpha TiOY (H2O2) 3, Hg2+ and EDTA can generate HgY2-, NH3, OH, and can continue to generate Hg (NH3) Y2- and Hg (OH) Y3-. If the ammonia solution pH=10, titrated with EDTA Hg2+, the total concentration of the buffer (i.e. increased CNH4++NH3) at lgK, the HgY value is increasing or decreasing? The titration jump range is increasing or decreasing? Explain the reason. Answer: because lgK HgY2-= lgKHgY2- LG Hg alpha LG alpha Y+lg alpha HgY2- Because the alpha HgY2-= alpha HgY2- alpha (NH3) + HgY2- (OH) - 1 increase of total concentration of buffer, [NH3] increased, [OH-] constant, HgY2- (NH3) increased, alpha HgY2- (OH) constant, alpha HgY2- increases, lgK, HgY2- increase, jump range increases. 4, metal ion is EDTA complex low metal ion is more stable. But for Ti (IV) and Ti (III), KTi (III) YKTi (IV) Y, a brief description of the reason for trying. Answer: because of Ti (IV) is in the form of complex with EDTA TiO2+, the number of the five membered ring structure such that the EDTA generated complex in less than Ti (III) EDTA complexes, and the stability is high, namely KTi (III) YKTi (IV) Y 5, 10-2mol? L-1 Zn2+ about precipitati