铜及其合金的表面钝化2涂装抗蚀性能的电化学测试.PDF

冯绍彬等 　铜及其合金的表面钝化涂装抗蚀性能的电化学测试 铜及其合金的表面钝化涂装抗蚀性能的电化学测试 冯绍彬 ,商士波 ,包祥 ,冯丽婷 (郑州轻工业学院材料与化学工程学院 , 河南 郑州 450002) 　　[摘 　要] 　表面钝化与涂装工艺相结合可显著提高铜及其合金的防腐性能。采用电化学工作站对涂层腐蚀电流进行 ( ) 5 Ω 定量测量 ,其结果显示 ,常规的涂装试样 ,在 3 % NaCl 盐水溶液中浸泡 1 天 ,测得腐蚀电阻 R c 为 3. 56 ×10 。钝化处理 后再涂装的试样测试结果为无穷大。盐水浸泡 5 天后 ,前者 95 %表面受到不同程度的腐蚀 ,后者仍然正常。后者浸泡 15 6 Ω 天的腐蚀电阻为 2. 31 ×10 ,仍高于前者浸泡 1 天的数据。钝化涂装工艺可用于室外及抗腐蚀性能要求较高的铜及其合 金制品的表面防护装饰。 [ 关键词] 　苯骈三氮唑 ;钝化 ;涂装 ;腐蚀电阻 ( ) [ 中图分类号]TG174. 3 　 　 　 [文献标识码]A 　 　 　 [文章编号]1001 - 3660 2005 01 - 0062 - 02 Electrochemistry Measurement of Anticorrosion on the Surface of Copper and its Alloy Treated by Passivationpainting FENG Shaobin , SHANG Shibo , BAO Xiang , FENG Liting (Department of Materials Chemical Engineering ,Zhengzhou Institute of Light Industry , Zhengzhou 450002 , China) [ Abstract ] 　The corrosion resistance of copper and its alloy may be improved remarkably by the method of com bination of surface passivation and painting technology. Ihe electrochemistry workstation was adopted to measure corro sion current of coating quantitatively. The results show that the corrosion resistance (Rc) of sample with routine paint 5 Ω ed is 3. 56 ×10 after dipping in 3 % NaCl solution for one day , and that of sample with passivated and painted again is infinite. After dipping for 5 days , 95 percent of the surface of the former is corroded to different extent and