固溶处理对Al_Zn_In阳极元素分布和电化学性能的影响.pdfVIP

30 1 Vol . 3 0 No . 1 2 0 0 9 2 TRANSACTIONS OF MATERIALS AND HEAT TREATMENT February 2 00 9 AlZnIn 齐公台, 邱于兵, 蔡启舟, 冉 伟 ( , 3007 ) : Al2Zn003In 510 ! 10h+ ∀ 510 ! 10h+ ∀ , (EPMA) , , : Zn FeSi , AlZn , Zn AlZn , : ; ; ; ; : TG1 62; TG1569 : A : 1009626 (2009) Influence of heat treatment on elements distribution and electrochemical properties of AlZnIn anode QI Gongtai, QIU Yubing, CAI Qizhou, RAN Wei ( School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology, Wuhan 3007 , China) Abstract:The Al5Zn003In alloy anodes were treated at 510 for 10h, and then were cooled by air or water, respectively. A JXA8800 electron probe microanalyzer and an EDAX quantitative energy dispersive Xray analyser were used to examine the microstructure of the anodes before and after heat treatment, and electrochemical properties of the anodes were tested. By heat treatment, the solubility of Zn in aluminum is increased and that of Fe and Zn is retained unchange, the quantity of AlZn metallic compounds is evidently decreased, the strip precipitates along grain boundaries is broken to spheric shape. With the increasing of Zn content in aluminum matrix and the reducing of AlZn metallic compounds precipitated along grain boundaries, the hydrogen evolution corrosion and intergranular corrosion of the aluminum anode are weakened, and it leds to the high current efficiency for aluminum alloy anode. Key words: aluminum alloy; sacrificial anode; solution treatment; microstructure; electrochemical property [ 6,7] ,