单分散性纳米co3o4的制备及电化学性能研究 study on preparation and electrochemical performance of mono-dispersed nanosized co3o4.pdfVIP
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单分散性纳米co3o4的制备及电化学性能研究 study on preparation and electrochemical performance of mono-dispersed nanosized co3o4
单分散性纳米C0304的制备及电化学性能研究
黄可龙, 刘人生, 杨幼平, 刘素琴, 龚本利
(中南大学化学化工学院,湖南长沙410083)
热法制备了约15
了表征;并对其电化学性能进行了测试,结果表明,采用水热法制备的单分散性纳米C030。的电化学性能优良;20次
循环后比容置保持有555
mAh/g。
关键词:单分散性;纳米颗粒;四氧化三钴;负极材料
912.9 文章编号:1002—087
中图分类号:TM 文献标识码:A X(2007)09—0680—03
on andelectrochemicalof
Studypreparation performance
nanosized
C0304
mOnO—disperSed
HUANG Ren-sheng,YANG Ben-li
Ke—long,LIU You—ping,L1USu—qin,GONG
South Hunan
ofChemistryChemical 410083,China)
(College Engineering,CentralUniversity,Changsha
Abstract: withthe sizeof15nmwas
Mono—dispersedsphericalC0304 particle synthesizedsuccessfullyby
method ascobalt as as
usingCo(N03)2·6H20 salt,NH3·H20-NH4Clprecipitator,H202oxidant,water
hydrothermal
as wascharacterized
andn-butanolas diffraction
solvent,polyethyleneglycoldispersant.Theproduct by×一ray
transmissionelectron electrochemicalofthe
(XRD)and microscopy(TEM).Theperformancessamplessynthesized
methodwerealso demonstratedlithium and
byhydrothermal investigated.Theyhigh storagecapacitygood
20 of retained555
nano-C0304
cyclability.Aftercycles,thedischargecapacity mAh/g.
materials
KeyWOrds:mono—dispersed;nanoparticles;C03
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