HFCs混合制冷剂热力性质的研究_吴献忠.pdf

《》2003 2 HFCs (　　200070) 　　 (　　200093) 　　PRHuron-Vidal , 10 HFC , NRTL , Gibbs S NRTL R407C R404A R32/R125/R134a R125/ R143a/R134a , , 0.42%, 。 R32/R125 R407C 。 　;;;;;; Study on Thermodynamic Properties of HFCS Refrigerant Mixtures ☆ By Wu Xianzhong , Li Mei ing and Kong Yi ☆Shanghai Ref rigerating Mac hine Works, China Abstract　To calculate thermodynamic properties of ternary refrigerant mixtures, the binary interaction parameter of the NRTL excess Gibbs free-energy model for ten groups of HFC (hydrofluorocarbon)refrigerant mixtures were correlat- ed by the vapor liquid equilibrium experimental datawiththe -Requation of state and the Huron-Vidal original mix- ture rules inthe study.At the same time, the vapor-liquid equilibrium of ternary refrigerant mixtures of R32/R125/ R134a and R125/R143a/R134a has been predicted with determined interaction parameters.Calculated results showed a good agreement with the experimental data, especially the average deviations of bubble point pressure were less than 0.42%.At last, the characteristics of the refrigeration cycle with R32/R125 and R407c are analyzed and discussed. Keyw ords 　engineering thermal physics, thermodynamic properties, equation of state, refrigerant mixtures, mixing rules, activity coefficient, refrigerating cycle analysis 1　 。 , PR 。 R22 、Huron -Vidal Gibbs R502 , NRTL , 10 CFC HFC ,