温泉管线矿物结垢与温泉水质组成之影响机制初步研究.PDFVIP

第二屆資源工程研討會論文集 溫泉管線礦物結垢與溫泉水質組成之影響機制初步研究 1 2 1 1 1 2 張竝瑜 、謝政道 、李孫榮 、蔡瀛逸 、陳煜斌 、郭萬木 摘要 本研究以水質模擬程式進行溫泉水對於溫泉管線與設備之沉澱與結垢潛勢分析，由潛勢分析結果顯示，多 數溫泉中過飽和之礦物主要為方解石、白雲石、針鐵礦、赤鐵礦、菱鐵礦、霰石等。為驗證潛勢分析結果，本 研究另採取溫泉管線結垢礦物進行 X 光繞射分析，並進行水質反應模擬分析，以了解可能生成機制。樣本來源 分別為花蓮瑞穗溫泉，知本東台飯店以及寶來國蘭山莊。比較反應模擬分析與礦物Ｘ光繞射分析之結果，瑞穗 溫泉對霰石以及方解石、白雲石等碳酸鹽礦物相呈現過飽和之狀態，而Ｘ光繞射分析之結果也呈現瑞穗、知本 等地溫泉結垢以霰石為主要礦物相，寶來溫泉則以方解石為主。由於寶來水質對方解石呈現未飽和狀態，加上 模擬分析顯示溫度下降對結垢礦物之產生影響有限，若根據現場條件加以曝氣，碳酸鹽類礦物將由於曝氣而增 加，顯示曝氣應為造成寶來方解石沉澱之主因。另外，知本之溫泉水含極少量之鈣離子組成，卻仍於溫泉管線 中發現霰石為主之碳酸鹽礦物結垢，由當地地表水之組成與模擬分析推測，其成因可能來自於地表水混入所造 成。 關鍵詞： 溫泉、水質模擬分析、結垢礦物、 X 光繞射分析。 ABSTRACT Geochemical modeling was conducted to analyze the mechanisms of minerals deposited in the hot spring pipelines. The calculation of saturation index (SI) shows that the minerals oversaturated frequently in hot springs are calcite, dolomite, goethite, hematite, siderite and aragonite. Analysis results of three hot spring samples, Re-Shue, Chi-Ban, Bao-Lai, were selected to further model the mechanisms that result in mineral deposits in the pipelines. Deposits collected from the pipeline in these hot springs were analyzed using X-ray diffraction (XRD). Calculation of SI indicates that Re-Shue hot spring is oversaturated to aragonite, dolomite and calcite. XRD analysis shows the major mineral deposit is aragonite in Re-Shue and Chi-Ban, and calcite in Bao-Lai. Modeling results show that the aragonite can be precipitated from the Bao-Lai hot spring if the dissolved CO2 is released from water to the air as the field condition. Calculation of SI also shows Chi-Ban hot spring is unsaturated to calcite. A modeling of mixing hot