混合电极电流密度分布的数值模型 mathematical model of mixed electrode current density distribution.pdfVIP

研 究 与 设 计 混合电极电流密度分布的数值模型 冯 毅 1,2， 解晶莹 1,2 (1. 中国科学院 上海微系统与信息技术研究所，上海 200050 ；2. 中国科学院 研究生院，北京 100049) 摘要：根据 Bulter- Volumer 和 Fick 定律建立了一维的 LicoO /Limn O 混合(材料) 电极的数值模型。 基于模型，研究了 2 2 4 两种材料在恒电流充放电过程中的电流密度分布，并计算了粒度、组分含量、信率对其电流密度分布的影响。 计算结果 表明，恒电流充放电情况下，两种材料的电流密度分布不均一：单一组分最犬电流密度值随粒度和信率的增犬而增犬， 随含量的增犬而减小。 在放电初期和末期， 电流主要分布在 LicoO2 上， 而在充电的初期和末期， 电流主要分布在 Limn O 上。 2 4 关键词：混合电极；数值模型；电流密度分布 中图分类号：Tm 912.9 文献标识码：A 文章编号：1002- 087 X(2007)04- 0273- 04 mathematical model of mixed electrode current density distribution FENG Yi1,2, XIE Jing-ying1,2 ( 1.Shanghai Institute of microsystem and Information Technology , CAS, Shanghai 200050, China ； 2.Graduate School of CAS, Beij ing 100049, China) Abstract: A one- dimension mathematical model with LicoO /Limn O mixed cathode was developed base on 2 2 4 Bulter- Volumer eguation and Fick law. The current density distributions of two compositions during charge- discharge process were studied and then the effects of compositions content, particle radius and discharge current on current density distribution were calculated by the model. The results show that current density distribution is non- uniform and the maximum current density of composition increases with particle radius and discharge current while decreases with the content. At the start and end of discharge process the current density was mainly loaded on LicoO , while at the st