Coatings unipd.it（涂料unipd.it）.pdf

Coatings Bressanone Sept. 2006 Coatings 1 Choice of a Suitable Coating Method • Requirements to the coating material (chemical composition, purity, crystallinity, materials properties) • Thermal stability of the substrate material • Adhesion of the coating under certain conditions (temperature, humidity, sunlight, etc.) • Throughput • Costs for investments, running costs • Environmental aspects Bressanone Sept. 2006 Coatings 2 1 Comparison Sol-Gel Processing / CVD Sol-Gel Processing CVD •larger variety of precursors •non-oxidic materials can also be deposited •many processing options •no shrinkage during annealing •preparation of inorganic-organic •epitactic growth and selective hybrid materials possible deposition possible •generation of complex micro- and •better control of film growth nanostructures (incl. porosity) possible •low thermal stress of the substrat •simple coating techniques Bressanone Sept. 2006 Coatings 3 Preparation of Lead Zirconate Titanate (PZT) – A Comparison Solid state reaction Sol-gel processing PbO + TiO + ZrO Pb(OAc) · 3 H O + Ti(OPr) + 2 2 2 2 4 Zr(OPr)4 + acetylacetone 750 - 1100 °C several h PZT Sol Pb(Zr0.53Ti0.47)