Impedance spectroscope of lithium electrodes_ Part 2. The behaviour in propylene carbonate solutions — the significance of the data obtained英文翻译.pdf

Journal of Electroanalytical Chemistry, 367 (1994) 15-25 15 Impedance spectroscopy of lithium electrodes Part 2. The behaviour in propylene carbonate solutions - The significance of the data obtained Doron Aurbach l and Arie Zaban Department of Chemistry, Bar-Ban University, Ramat Gan 52900 (Israel) (Received 21 January 1993; in revised form 17 May 1993) Abstract The interphases formed on Li electrodes in various propylene carbonate solutions were investigated using impedance spectroscopy. The influences of temperature and solution composition (salt, concentration, additive and contaminants) were studied. The data obtained were modelled by equivalent circuit analogues of five RC sections in series. Calculations based on various experiments indicate that the various RC sections in this equivalent circuit analogue were related to different layers which constitute the Li-solution interphase. It was possible to calculate thickness and resistivity of the various layers based on the assumption that changes in the composition and structure of the surface films strongly affected their resistivity but not their relative permittivity, because the permittivity of the various surface species formed on Li are very similar. This calculation seemed to show that the interphase changes considerably in its structure and electrical properties from Li to the solution. 1. Introduction The present work is aimed at ascertaining the signif-