铝-碱溶液水解制氢技术研究 study of hydrogen generation from the hydrolysis of aluminum in naoh solution.pdfVIP
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铝-碱溶液水解制氢技术研究 study of hydrogen generation from the hydrolysis of aluminum in naoh solution
铝一碱溶液水解制氢技术研究
范美强1一,徐芬1,孙立贤1
(1.中国科学院大连化学物理所,辽宁大连116023;2.中国科学院研究生院,北京100039)
摘要:考察了铝粒径、碱浓度、温度、球磨时间以及添加剂等因素对铝粉水解性能的影响。并通过水解实验和扫描电镜分
析。实验结果表明。铝粒径的减小、碱浓度和温度的增加、球磨时间的延长以及添加剂的加入提高了铝粉在碱溶液的水
解速率。例如:铝一10%(质量分数)盐混合物球磨后,铝粉的水解速率由球磨前的136 mU
mL/(min·g)增加到604
(min·g)。采用铝一碱溶液制氢,可为燃料电池提供不含有毒气体的氢气。实现现场制氢、供氢,有效解决氢气储存问题。
关键词:铝粉;高能球磨;碱溶液
中图分类号:TM911文献标识码:A 文章编号:1002—087
X(2009)06—0493—04
of
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