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水基cofe2o4离子型磁性液体体系粒径研究
研究·分析·实验
水基CoFe O 离子型磁性液体体系粒径研究
2 4
1 2
白 浪 ,于 娟
(1. 攀枝花学院 材料科学与工程学院,四川攀枝花 617000;
2. 攀枝花学院 电气信息工程学院,四川攀枝花 617000 )
摘 要:采用 Massart 法制备了水基 CoFe2O4 离子型磁性液体。分别用XRD 、TEM 和 VSM 对样品进行测
量与表征,计算得出磁性液体中纳米微粒平均粒径,利用 TEM 和 VSM 方法得出粒径分布。结果表明,磁性液
体中微粒粒径平均在 10nm 左右,呈对数正态分布,基于 XRD 计算的平均粒径小于 TEM 平均粒径而大于 VSM
平均粒径。磁性液体中存在的块状、环状以及半环状预团聚体、微粒结晶程度及其表面非磁性层、TEM 样本的
选取等均会对测量结果产生影响。讨论了三种测量方法的优缺点和适用范围。
关键词:磁性液体;粒径;粒径分布;X 射线衍射;透射电镜;振动样品磁强计
中图分类号:TM27 文献标识码:A 文章编号:1001-3830(2012)06-0029-05
Study of particle diameter of water-base CoFe O ionic ferrofluids
2 4
1 2
BAI Lang , YU Juan
1. School of Material Engineering, Panzhihua University, Panzhihua 617000, China;
2. School of Electric and Information Engineering, Panzhihua University, Panzhihua 617000, China
Abstract: Water-base CoFe O ionic ferrofluids has been prepared by Massart method. The sample was
2 4
measured and characterised by XRD, TEM and VSM respectively, and the mean diameter of nano-particles in
ferrofluids were calculated according to the experimental results. The diameter distribution were acquired according to
TEM and VSM results. The result showed that the diameter shows a lognormal distribution and the mean diameter is
about 10nm. The mean diameter based on XRD was bigger than that based onVSM and smaller than that based on TEM.
The analysis showed that the bulk, ring-like and half ring-like aggregation in ferrofluids,
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