金属有机物化学气相沉积法制备负载型纳米TiO高校化学工程学报.PDF

19 1 No.1 Vol.19 2005 2 Journal of Chemical Engineering of Chinese Universities Feb. 2005 1003-9015(2005)01-0119-05 TiO2 , , , 甦 (, 310027) TiO2 TiO2 XRD 773 K TiO2 873 K TEM 8 (wt) TiO2 10~20 nmBET 6 (4-CP) TiO2 P25 10 X505 TQ426.8 TQ134.11 A Preparation and Evaluation of Nanosized TiO Supported on Activated Carbon by 2 Metal-Organic Chemical Vapor Deposition XU Su, ZHOU Ming-hua, ZHANG Xing-wang, LEI Le-cheng (Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China) Abstract: For nanosized powder TiO2 , an effective photocatalyst, the difficulty in recovery and dispersion as well as the aggregation tendency of the suspended particles, would greatly limit its application in actual wastewater treatment. To overcome these problems, the atmospheric pressure metal-organic chemical vapor deposition (MOCVD) technology was used to load TiO2 onto the surface of activated carbon. XRD results show that the TiO2 calcined at 773 K is in anatase phase and in rutile phase for those calcined at 873 K. The TEM results show that the suitable amount of supported titania is 8 (wt), in which the TiO2 particle sizes are in the range of 10 to 20 nm, and compared with the activated carbon, the BET surface area is only reduced by 6 . When using in the photocatalytic degradation of 4-chlorophenol (4-CP), the photocatalytic activity of the supported TiO2 prepared by MOCVD