锂离子电池用Si_Fe复合电极材料的制备和其性能.pdf

第 42 卷第 4 期 中南大学学报( 自然科学版) Vol.42 No.4 2011 年 4 月 Journal of Central South University (Science and Technology) Apr. 2011 锂离子电池用Si-Fe 复合电极材料的制备及其性能 杨娟，唐晶晶，娄世菊，邹幽兰，周向阳 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘要：以Fe 粉与 Si 粉为混合粉原料，研究经机械球磨、退火热处理后混合粉的形貌、结构与恒电流充放电性能， 同时对比研究 Si-Fe 合金粉的性能。研究结果表明：混合粉原料经过高能机械球磨，生成了 Si-Fe 合金相，而 Si-Fe 合金的生成改善了 Si 作为锂离子电池负极材料的循环性能；与工业级 Si-Fe 合金负极材料相比，合金化程度影响 了合金材料的电化学性能，合金化程度越高，合金材料电化学性能越好；而退火热处理也可以在一定程度上改善 合金材料的脱嵌锂性能。 关键词：Si-Fe 合金；锂离子电池；Si 基负极；退火 中图分类号：O646 文献标志码：A 文章编号：1672−7207(2011)04−0859−06 Preparation and performance of Si-Fe composite materials for lithium ion batteries YANG Juan, TANG Jing-jing, LOU Shi-ju, ZOU You-lan, ZHOU Xiang-yang (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: Si-Fe composites were prepared by ball-milling a mixture of Si and Fe powders. The morphology, phase structures and electrochemical performances of the composites were investigated after ball-milling and annealing. An industrial Si-Fe alloy material was studied as a comparison. The results show that Si-Fe alloy phase generated in the composites after ball-milling can improve the cyclic performance of Si. By comparing the Si-Fe alloy with the industrial Si-Fe alloy, it is shown that alloying degree affects the electrochemical performance of alloy materials. Annealing process can improve the electrochemical performance of the composite to some extent. Keywords: Si-Fe alloy; lithium ion battery; Si-based anode materials; annealing 锂离子电池硅基负极材料由于理论容量达到