水分散性羟基丙烯酸树脂及其应用(2)资料.docxVIP

水分散性羟基丙烯酸树脂及其应用马玲玲，杜晶，周萌萌，曹飞，肖继君（河北科技大学，材料科学与工程学院，石家庄 050018）摘要：本文采用甲基丙烯酸甲酯（MMA）、甲基丙烯酸羟乙酯（HEMA）、苯乙烯（ST）、甲基丙烯酸（MAA）等单体为主要原料，利用溶液聚合法成功地合成了水分散性羟基丙烯酸树脂。通过红外光谱、格式管粘度法、差示扫描量热法、化学滴定法分别对树脂的结构、粘度、玻璃化转变温度、酸值和羟值进行了表征。研究结果表明合成的羟基丙烯酸树脂和预期的结构相符；随着链转移剂用量的增加或者反应温度的提高，羟基丙烯酸树脂的粘度和玻璃化转变温度都降低；而且甲基丙烯酸和链转移剂用量的增加，羟基丙烯酸树脂的水分散性越来越好。以该羟基丙烯酸树脂为羟基组分， N-3390为异氰酸酯组分制备了性能优异的聚氨酯清漆。关键词：水分散羟基丙烯酸树脂玻璃化转变温度应用Water-Dispersible Hydroxy Acrylic Resin and ApplicationAbstract: In this paper, hydroxyl acrylic resin with water-dispersion was successfully synthesized by using methyl methacrylate (MMA), hydroxyethyl methacrylate (HEMA), styrene (St), methacrylic acid (MAA) as raw materials via the method of solution polymerization. The structure, viscosity, glass transition temperature, acid value and hydroxyl value of hydroxyl acrylic resin were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), format pipe viscosity method, differential Scanning Calorimetry (DSC) and chemical titration, respectively. The results show that synthetic hydroxyl acrylic resin corresponding to the expected structure. With the increase in dosage of chain transfer agent or reaction temperature, both the viscosity and glass transition temperature of hydroxyl acrylic resin increase. With the increase in content of methyl methacrylic acid and chain transfer agent, water-dispersion of hydroxyl acrylic resin increases. Polyurethane varnish with excellent properties was prepared by hydroxyl acrylic resin and N-3390 as hydroxy and isocyanate component, respectively.Key Words: water-dispersion; hydroxyl acrylic resin; glass transition temperature; application1．引言传统的溶剂型涂料排放到空气中的有机化合物和污染大气的有机挥发物(VOC，Volatile Organic Compound)严重超标[1]。VOC是现代社会中重要的污染源，空气中的VOC会被人们直接吸入体内而威胁人体健康。随着人们环保意识的增强和各国环境保护法律法规的相继出台，涂料中挥发性有机化合物(VOC)的排放问题引起了世界各国的关注[2-4]。传统的溶剂型涂料将逐渐退出历史的舞台，而高性能、低污染、多功能的环保型涂料越来越受到大家的青睐，发展绿色环保型涂料逐渐成为未来涂料技术的发展趋势[5-7]。其中，水性涂料以其优异的综合性能脱颖而出[8]。水性涂料最大的优点是最大限度地降低了有机挥发性溶剂的用量，符合环保要求，水性涂料生产安全、不易燃、降低了毒性和异味，生产设备易清洗[9]。高性能水性树脂的问世，使得水性涂料得到迅速发展。