荧光发光机理.pptVIP

用来表示原子(或离子)所处能量状态的符号，称为光谱项(spectral term)。 其能量状态与总自旋量子数S，总轨道量子数L和总角动量量子数J 有关，光谱项通常表示为2S+1LJ。 对应L为0, 1, 2, 3, 4, 5…数值，分别用S、P、D、F、G、H…表示。 例如，Pr3+，有两个自旋平行的f 电子，则S = 1/2+1/2 = 1，对f电子，磁量子数有7个: 3, 2, 1, 0, –1, -2, -3, 要使 L= lj为最大，2个电子应该有最大的M = ∑m，这就是 两个电子分别应占有m= 3, 2，因此M = 5，即L= 5. 而J的取值范围，对于轻稀土J = |L - S|；则J = 4 ， 因此Pr3+的基态光谱项为3H4 Photoluminescence mechanism :Antenna Effect 5D0 (Eu3+) :17250 cm-1 ET(TA) :25160 cm-1 ET(BPC) :22083 cm-1 最佳匹配能级差： 3500-5000 cm-1 Reviewer 1 asked about the coupling to donor energy levels. This question was side-stepped. No evidence is given for the location of donor triplet or charge transfer states. No mention is given of the mechanism of energy transfer (e.g. from which donor state and if it is exchange or multipolar interaction). excitation spectra: 250–390 nm ascribed to transitions from ground state S0 to first excited state S1 (?, ?*) of organic guests. ~280 nm attributed to transitions of charge transfer (CT). The series of sharp peaks around 350-500 nm are intra-4f electronic transitions of Eu3+. The stronger intensities of broad bands from BPC and TA than that from Eu3+ themselves indicate Eu3+ are excited mainly via a sensitized process, rather than a direct excitation. (318 nm for BPC, and 300 nm for TA) location of donor triplet states can be determined by measuring luminescence spectra of their corresponding Gd3+ complexes as model compounds. The main modes of resonance energy transfer include: Exchange interaction and multipolar interaction exchange interaction requires that donor and acceptor have overlapped wave functions, which means that the lattice spacing of them should be 0.3-0.4 nm. The donor and acceptor will have a larger distance 0.3-0.4 nm, thus theoretically, the transfer energy mechanism for BPC and TA donors to Eu3+ acceptor may belong to a multipolar interaction. 2. Reviewer 3 noted that the spectra presented in Fig 4 utilized 395 nm excitation: i.e.