微波加热配碳还原分解铁酸锌的工艺及机理研究 - 有色金属（冶炼部分）.doc

微波加热配碳还原分解铁酸锌的工艺及机理研究 王欣1,2,3，杨大锦4，彭金辉1,2,3，巨少华1,2,3 （1.昆明理工大学 冶金与能源工程学院，昆明 650093；2.非常规冶金教育部重点实验室，昆明 650093；3. 微波能工程应用及装备技术国家地方联合工程验室，昆明 650093；4.昆明冶金研究院 650093） 摘要：研究了利用微波配碳还原焙烧分解铁酸锌的工艺及机理。利用碳气化控制、化学控制及扩散控制模型研究了样品中铁酸锌分解的动力学行为了微波功率反应温度配碳比和铁酸锌分解的。结果表明样品的微波加热碳热还原试验的控制步骤为碳气化控制，活化能39.21 kJ/mol，在微波加热850 ℃、C/ZnFe2O4质量比为1∶4、粒径7489 μm、微波功率18 kW、加热时间60 min的条件下的分解率达到90%。 关键词：动力学铁酸锌活化能微波arbothermic Process and Mechanism Study on Zinc Ferrite Decomposition with Microwave WANG Xin1,2,3, YANG Da-jin4, PENG Jin-hui1,2,3, JU Shao-hua1,2,3 (1. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Key Laboratory of Unconventional Metallurgy, Ministry of Eduaction, Kunming 650093, China; 3. Engineering Laboratory of Microwave Application and Equipment Technology, Kunming 650093, China; 4. Kunming Metallurgy Research Institute, Kunming 650093, China) Abstract: The process and mechanism of carbothermic reduction with microwave of ZnFe2O4 were studied. The decomposition kinetics of ZnFe2O4 was carried out with models of carbon gasification, interfacial area of mass transfer, and diffusion control. The effects of microwave power, reaction temperature, ratio of C/ZnFe2O4, and particle size on decomposition rate of ZnFe2O4 were investigated. The results show that the controlling model of decomposition of ZnFe2O4 is carbon gasification control with the kinetics of ln(1-3α)=kt and activation energy of 39.21 kJ/mol. The decomposition rate of ZnFe2O4 is up to 90% under the conditions including microwave heating temperature of 850 ℃, mass ratio of C/ZnFe2O4 of 1/4, particle size of 74~89 μm, microwave power of 1.8 kW, and reaction time of 60 min. Key words: kinetics; zinc ferrite; activation energy; microwave; mechanism 锌被广泛应用于制造各种压铸件[1]。镀锌工业消耗量占世界锌消耗量的50％。我国是世界第一大产锌国，国内常见锌矿中常伴生有815%的铁[2]。 目前锌厂的常规冶炼工艺焙烧浸出电积在常规焙烧过程中，铁酸锌成[3]导致锌的总回收率仅有7580%，且产生大量浸出渣常规酸浸及碱浸很难完全溶解铁酸锌，常需要高温高压的浸出条件[4]。湿法浸出渣回收铁酸锌中的锌主要工艺有烟化法还原焙烧电热法热酸浸出法[5-6]。常规火法工艺需要较高的温度和较