课件电化学数据.doc

各种常用金属的密度：单位 g/cm3 ?AL：2.7 Fe： 7.85 ?? 铅阳极板 ? ? ? ? ?11.33黄铜 ? ? ? ? ? ?? 8.80 53g/ cm3 锰 7.43? 汞 13.6? 锡 7.3? 锌 7.2? 钛 4.51? 钴 8.9? 钨 19.3? 镍 8.85 标准电极电位表 半反应 E0（伏） F2(气) + 2H+ + 2e = 2HF 3.06 O3 + 2H+ + 2e = O2 + 2H2O 2.07 S2O82– + 2e = 2SO42– 2.01 H2O2 + 2H+ + 2e = 2H2O 1.77 MnO4– + 4H+ + 3e = MnO2(固) + 2H2O 1.695 PbO2(固) + SO42– + 4H+ + 2e = PbSO4(固) + 2H2O 1.685 HClO2 + H+ + e = HClO + H2O 1.64 HClO + H+ + e = 1/2 Cl2 + H2O 1.63 Ce4+ + e = Ce3+ 1.61 H5IO6 + H+ + 2e = IO3– + 3H2O 1.60 HBrO + H+ + e = 1/2 Br2 + H2O 1.59 BrO3– + 6H+ + 5e = 1/2 Br2 + 3H2O 1.52 MnO4– + 8H+ + 5e = Mn2+ + 4H2O 1.51 Au(III) + 3e = Au 1.50 HClO + H+ + 2e = Cl– + H2O 1.49 ClO3– + 6H+ + 5e = 1/2 Cl2 + 3H2O 1.47 PbO2(固) + 4H+ + 2e = Pb2+ + 2H2O 1.455 HIO + H+ + e = 1/2 I2 + H2O 1.45 ClO3– + 6H+ + 6e = Cl– + 3H2O 1.45 BrO3– + 6H+ + 6e =Br – + 3H2O 1.44 Au(III) + 2e = Au(I) 1.41 Cl2(气) + 2e = 2Cl 1.3595 ClO4– + 8H+ + 7e = 1/2 Cl2 + 4H2O 1.34 Cr2O72– + 14H+ + 6e =2Cr3+ + 7H2O 1.33 MnO2(固) + 4H+ + 2e = Mn2+ + 2H2O 1.23 O2(气) + 4H+ + 4e = 2H2O 1.229 IO3– + 6H+ + 5e = 1/2 I2 + 3H2O 1.20 ClO4– + 2H+ + 2e = ClO3– + H2O 1.19 Br2(水) + 2e = 2Br – 1.087 NO2 + H+ + e = HNO2 1.07 Br3– + 2e = 3Br – 1.05 HNO2 + H+ + e = NO(气) + H2O 1.00 VO2+ + 2H+ + e = VO2+ + H2O 1.00 HIO + H+ + 2e = I– + H2O 0.99 NO3– + 3H+ + 2e = HNO2 + H2O 0.94 ClO– + H2O + 2e = Cl– + 2OH– 0.89 H2O2 + 2e = 2OH– 0.88 Cu2+ + I– + e = CuI(固) 0.86 Hg2+ + 2e = Hg 0.845 NO3– + 2H+ + e = NO2 + H2O 0.80 Ag+ + e = Ag 0.7995 Hg22+ + 2e = 2Hg 0.793 Fe3+ + e = Fe2+ 0.771 BrO– + H2O + 2e = Br – + 2OH– 0.76 O2(气) + 2H+ + 2e = H2O2 0.682 AsO8– + 2H2O + 3e = As + 4OH– 0.68 2HgCl2 + 2e = Hg2Cl2(固) + 2Cl– 0.63 Hg2SO4(固) + 2e = 2Hg + SO42– 0.6151 MnO4– + 2H2O + 3e = MnO2 + 4OH– 0.588 MnO4– + e = MnO42– 0.564 H3AsO4 + 2H+ + 2e = HAsO2 + 2H2O 0.559 I3– + 2e = 3I– 0.545 I2(固) + 2e = 2I– 0.5345 Mo(VI) + e = Mo(V) 0.53 Cu+ + e = Cu 0.52 4SO2(水) + 4H+ + 6e =