正极表面处理对mh-ni电池自放电性能影响 effects of the surface treatment of formed positive electrode on self-discharge performance of ni-mh batteries.pdfVIP
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正极表面处理对mh-ni电池自放电性能影响 effects of the surface treatment of formed positive electrode on self-discharge performance of ni-mh batteries
电池工业
正极表面处理对MH—Ni电池自放电性能影响
李晓峰,李加勇
(郑州轻工业学院材料与化学工程学院,河南省表界面科学重点实验室,河南郑州450002)
放电性能的影响。实验结果表明,CMC处理能明显降低镍电极的自放电率,但不能改善电池的自放
电性能;相反,PTFE处理虽不能降低镍电极自放电率,但却能明显改善电池的自放电性能。MH—Ni
电池的自放电性能可能与负极析出的H:在正极上的电化学氧化过程密切相关。
关键词:MH—Ni电池;自放电;镍电极;表面处理
Effectsofthesurfacetreatmentofformed electrode
positive
on ofNi-MHbatteries
self-dischargeperformance
LIXiao-feng,LIJia—yong
and andChemical
(Provinc/a/keylaboratoryofsurfaceinterface,DepartmentofM础edd Engtneering,
450002,China)
ZhengzhouUniversityofLightIndustry,Zhen@hou,Henan
Abstract:Thesurfaceoftheformed electrodesofNi—。MHbatteriesweremodified
positive separately
with the
polytetrafluoroethylene(P1下E)andcarboxymethylcellulose(CMC)andself-discharge
showedthatafterCMC
ofthebatterieswerestudied.Theresults self-
performance modification,the
rateofthe electrodeswas thebatteries7 rate
nickel reduced,but
discharge significantly self-discharge
hadlittle theother rateofthenickel
hand.after朋陌Emodification,the
change.On self-discharge
was
electrodeswasnot theoneofthebatteries reduced.The
lower,but significantly self—discharge
ofthebatteriesbe relativetotheelec
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