正十二硫醇自组装单层膜改善环氧涂层腐蚀防护性能的研究.pdf

2004 年第 62 卷 化 学 学 报 Vol. 62 , 2004 第 17 期 , 1612～1616 ACTA CHIMICA SINICA No. 17 , 1612 ～1616 正十二硫醇自组装单层膜改善环氧涂层腐蚀防护性能的研究 孔　燕　　张树永 　　李红娟 ( 山东大学化学与化工学院 　济南 250100) 通过在正十二硫醇自组装单层膜表面制备环氧树脂涂层的方法 ,在涂层/ 铜基体界面引入自组装界面层. 采用 X 射 摘要 　 线光电子能谱、电化学阻抗谱、阻抗 - 时间谱和相位角 - 时间谱等方法对硫醇自组装界面层及其对涂层腐蚀防护性能的影 响进行了研究. 结果表明 ,引入的自组装单层可极大地改善涂层的腐蚀防护性能. 论文还对自组装单层改善涂层腐蚀防护 性能的机理进行了探讨. 关键词 　涂层 ,腐蚀防护 ,机理 ,涂层/ 金属界面 , 自组装单层 Study of the Effect of nDodecanethiol Selfassembled Monolayer on the Improvement of Corrosion Protection of Epoxy Coating KONG, Yan 　　ZHANG, ShuYong 　　LI , HongJuan ( ) School of Chemistry and Chemical Engineering , Shandong University , Jinan 250100 Abstract 　By formation of epoxy coating on ndodecanethiol selfassembled monolayer on copper substrate , self assembled monolayer was introduced between epoxy coating and copper electrode. The formation of selfassembled interfacial ndodecanethiol monolayer and its effect on the corrosion protection of epoxy coating were evaluated using the Xray photoelectronic spectroscopy , electrochemical impedance spectroscopy , impedancetime transition , and phase angletime transition method. It was found that , the selfassembled interfacial monolayer can improve the corrosion protection of the epoxy coa