锌铈液流电池研究进展.DOCVIP

锌铈液流电池研究进展 谢志鹏，蔡定建，杨亮 （江西理工大学冶金与化学工程学院，赣州市，341000） 摘要：能源是经济发展和人们生活的重要物质基础。化石燃料的过度消耗加速了能源危机和环境污染的出现。新能源利用是解决能源问题和环境问题的必然选择。太阳能、风能和潮汐能等新能源发电具有间歇性的特点，给电网的安全稳定运行带来很大的挑战。储能技术是新能源开发的关键技术。在各种储能技术中，电化学储能日益受到重视。液流电池是一种高效大规模储能系统。锌铈液流电池是已知的单电池电压最高的水溶液电解质电池。本文阐述了锌铈液流电池的工作原理，从正半电池反应、负半电池反应和隔膜三个方面综述了当前的研究进展。指出了锌铈液流电池研究中需重点关注的基础问题。 关键词：稀土储能材料，新能源，液流电池，铈， Research progress of zinc-cerium redox flow battery XIE Zhi-peng , CAI Ding-jian, YANG Liang (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou，341000) Abstract: The energy is an important material basis for economic development and peoples living. While the excessive consumption of fossil fuels has accelerated the energy crisis and environmental pollution. The utilization of new energy is the inevitable choice of solving the energy and environmental problems. The new energy power generation such as solar, wind and tidal energy is intermittent. Thus it has brought great challenges to the safe and stable operation of power grids. The technology of energy storage is the key one in the development of new energy. In all kinds of energy storage technology, people have paid more and more attention to electrochemical energy storage. The redox flow battery is a large-scale and highly efficient energy storage system. It is known that the zinc-cerium redox flow battery is the aqueous electrolyte battery which has the highest single cell voltage . In this paper, the working principle of zinc-cerium redox flow battery has been described. The current researching development has been reviewed from three aspects such as reactions of the positive and negative half cells , as well as the membrane . The basic problems in zinc-cerium redox flow battery that need to be focused on have been pointed out. Key words: Rare Earth Material for energy storage, new energy, redox flow battery, cerium 基金项目：国家自然科学基金资助项目；江西理工大学校级课题（jxxj12022） 通信作者：谢志鹏（1973-），男，讲师，博士，研究方向为电化学储能技术。E-mail: zhpxie_06@126.co