三聚磷酸钠对建筑石膏水化进程的影响和缓凝机理研究.pdfVIP

2 6 6 硅 酸 盐 通 报 V ol. 26 N o. 6 2 007 12 BU LLE TIN OF TH E CH IN ESE CERAM IC SOC IETY D ecem b er 2007 彭家惠 张建新 瞿金东 吴 莉 李志坤 ( 400045 ) : X : ; ; 2p 1. 267eV ; : ; ; ; ; : TQ177 : A : 5( 2 007) 06210 5320 5 E ffect of Sod ium Tr ipolyphosphate on H ydrat ion Process of Bu il ding Gyp sum and Its R etard ingM ech an ism PENG Jia2hui, ZHANGJian2xin, QU Jin2dong,WU Li, LI Zhi2kun ( Deparmt en t of Construct ion M aterials Chongq ing Un iver sity Chongqing 400045 Ch ina) Abstr act: E ffect of sodium trip olyphosph ate on th e hydrat ion process ion concentrat ion and supersaturation degree in liqu id phase and crystal m orphology of bu ild ing gypsum was system ically invest igated. Furth ermore by u sing XPS techn ique its retarding m ech an ism was also an alyzed. The resu lts ind icate th at th e add ition of sod ium tripolyphosph ate slows down the hydrat ion h eat evolution decreases hydrationrate at early stage and prolongs th e induction period of bu ilding gypsum. A fter addit ion of sod ium tripolyphosph ate ion con centration and supersaturat ion degree of gypsum in liqu id phase is decreased the crysta l of dihydrate is coarsened an d the crystalm orphology is a ltered from n eedle2lik e to sh ort prism atic. XPSm easurem ent show s th e 2p electric bon din g energy of Ca e lem ent on th e surface of gypsum p artic les takes p lace