铜冶炼熔渣中铁组分迁移与析出行为的研究-有色金属冶炼部分.docVIP

添加剂对铜渣改性过程中磁铁矿相析出与长大的影响 曹洪杨1，王继民1，张力2，隋智通2 （1.广州有色金属研究院 稀有金属研究所，广州 510650；2.东北大学 材料与冶金学院，沈阳 110819） 摘要：采用高温氧化改性方法富集含铜熔渣铁。研究了添加剂种类对磁铁矿相析出与长大的影响，结合相图考察了添加剂作用下磁铁矿相结晶量、晶粒度及晶体形貌的变化，并初步探讨了添加剂的作用机理结果表明，添加2%5%的CaO量有利于磁铁矿相的析出；添加1%3%的CaF2对磁铁矿相的析出与长大、粗化有一定的促进作用；新型复合添加剂既降低了熔渣的度和熔化性温度，也提高了熔渣的碱性，对磁铁矿相析出、 长大的作用显著磁铁矿相体积分数达到41.5%42.4%，晶粒呈粗大等轴晶，晶粒尺寸50.255.6 μm，有利于改性渣中磁铁矿的选矿分离关键词：添加剂；铜渣；磁铁矿；析出；长大 TF534.2 文献标志码：A 文章编号：1007-7545（2013）06-0000-00 Effect of Additives on Precipitation and Growing of Magnetite during Modifying Progress of Copper Smelting Slag CAO Hong-yang1, WANG Ji-min1, ZHANG Li2, SUI Zhi-tong2 (1. Research Department of Rare Metals, Guangzhou Research Institute of Nonferrous Metals, Guangzhou 510650, China; 2. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China) Abstract: The iron in copper smelting slag was enriched with high temperature oxidation modification process. The effects of different kinds of additives on precipitation and growing behavior of magnetite phase were analyzed. The changes of quantity of crystallization, grain size and crystal morphology of magnetite phase under additives were investigated with combination of the analysis of phase diagram, and the mechanisms of action of additives were given a preliminary discussion. The results show that addition of 2%~5% CaO is in favor of magnetite precipitation, and 1%~3% addition of CaF2 can promote precipitation, growing and coarsening of magnetite. The new type of composition additives can obviously promote precipitation and growing of magnetite with the volume fraction of 41.5%~42.4% and 50.2~55.6 μm equiaxed grains. It is beneficial to separation of magnetite from modified slag by mineral processing. Key words：additive copper smelting slag; magnetite; precipitation; grow 我国每年铜冶炼渣产量高达800多万吨，含有0.2%5%的铜及40%左右的铁，同时含有金、银、锌、铅、镍、钴等多种有价金属，是宝贵的矿产资源目前，铜渣中有价组分回收主要采用选矿、湿法浸出、火法分离、真空处理和细菌浸出等[16]。王珩[7]以铜转炉渣为原料采用浮选磁选结合工艺选别铜、铁。魏明安[8]采用浮选工艺回收铜转炉渣中的铜，得到品位30.82%的铜精矿、回收率90.05%。李磊等[9]以CaF2为添加剂熔