氟硅氧烷共聚及表面性能的研究.docxVIP

氟硅氧烷共聚及表面性能的研究摘要本文通过自由基溶液聚合的方法采用全氟辛基三乙氧基硅烷 (PFAS)、　-γ(2,3-环氧丙氧基)丙基三甲氧基硅烷(GPTMS)和正硅酸乙酯（TEOS），通过溶胶－凝胶法制备了一种分子级复合、均质透明的包含碳硅双主链结构，侧链引入一定浓度的 CF3基团的氟硅氧烷低聚物。详细研究了不同PFAS/TEOS比例对共聚物材料表面润湿性能的影响。傅里叶红外光谱（FT-IR）,扫描电镜(SEM)和X射线光电子能谱分析（XPS）分析结果表明，本文所制备的氟硅氧烷共聚材料是一种分子级复合、均质透明的分别以碳和硅为主链的并行双主链结构的低聚物杂化材料。实验发现，CF3基团在材料表面富集程度高，表面疏水性能好。表面氟含量的降低将导致CF3基团含量下降，影响材料的疏水性能。关键词： 氟硅氧烷共聚物；接触角；分子量；表面能Synthesis and Surface Properties of Fluorosilicone CopolymersAbstractThis radical solution polymerization method by using perfluorooctanetriethoxysilane (PFAS),-γ (2,3 - epoxy propoxy) trimethoxysilane (GPTMS) and TEOS (TEOS), through the sol - gel method, a molecular compound, homogeneous and transparent double main chain containing carbon-silicon structure, side chain to introduce a certain concentration of fluoride CF3 groups siloxane oligomers. Detailed study of the different PFAS / TEOS molar ratio on the copolymer surface wettability.Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analysis results show that the prepared material is a fluorosiloxane copolymer molecular compound, homogeneous and transparent Respectively the main chain of carbon and silicon parallel double main-chain structure of the oligomer hybrid material.It was found that, CF3 groups in a high degree of surface enrichment, surface hydrophobicity and good performance. Reduce the fluorine content of the surface will result in decreased CF3 groups, the hydrophobic properties of materials.Key Words：Fluorosilicone copolymer；Contact angle；Molecular weight；Surface energy目 录摘要IAbstractI前言1第1章文献综述11.1以有机硅树脂为基料的低表面能材料11.2有机氟低表面能材料11.3硅-氟树脂低表面能材料11.4含氟硅聚合物的合成[29-33]11.4.1 乳液聚合11.4.2 溶液聚合11.4.3 本体聚合11.4.4 氢化硅烷化反应11.5 含氟硅聚合物的应用11.5.1 氟硅涂料11.5.2 脱膜剂11.5.3 织物、皮革、纸张的整理剂11.5.4 润滑剂11.5.5 舰船防腐防污11.5.6 表面活性剂领域11.5.7小结1第2章实验方法及表征手段12.1实验仪器12.2实验材料和试剂12.2 2.3性能表征12.3.1共聚物结构分析12.3.2 共聚物微观结构分析12.3.3 表面的元素分析12.3.4 润湿性12.4实验步骤12.4.1 基材预处理12.4.2 聚合12.4.3 杂化材料制备1第3章氟硅氧烷共聚结构与形貌13.1