热喷涂Fe基非晶涂层耐腐蚀性与孔隙率研究进展-表面技术.PDF

表面技术 第 46 卷 第 5 期 ·238 · SURFACE TECHNOLOGY 2017 年 5 月 热喷涂 Fe 基非晶涂层耐腐蚀性与孔隙率研究进展 姜超平，刘王强 （长安大学 材料科学与工程学院，西安 710064） 摘 要：热喷涂Fe 基非晶合金涂层的综合性能优异，特别是在耐磨、耐腐蚀方面具有传统晶体材料无可比 拟的优势，因而广泛应用于材料表面的防护领域。然而热喷涂涂层为典型的层状结构，涂层内部会存在一 定量的孔隙，致使涂层耐腐蚀性能下降。首先介绍了热喷涂Fe 基非晶涂层的腐蚀机理及其影响因素，总结 了热喷涂涂层孔隙产生的机制、分类和影响因素。接着重点介绍了孔隙与热喷涂Fe 基非晶涂层耐腐蚀性之 间关系的研究进展。最后，通过对热喷涂涂层的形成过程与孔隙形成机理进行分析，粒子铺展变形能力差 是显著影响涂层形成时粒子相互嵌套叠加和变形能力的主要原因。所以，Fe 基非晶涂层可以从改变喷涂粉 末成分和粒度、第二项粒子加入及喷涂工艺参数优化等措施，来改善粒子铺展变形能力，提高致密度。采 用激光快速表面重熔技术对涂层微表层进行快速重熔处理，同样可以达到降低涂层孔隙率、提高涂层耐腐 蚀性的目的。 关键词：Fe 基非晶合金；热喷涂；涂层；孔隙率；激光重熔；腐蚀机理 中图分类号：TG174.4 文献标识码：A 文章编号：1001-3660(2017)05-0238-06 DOI ：10.16490/j.cnki.issn.1001-3660.2017.05.038 Porosity and Corrosion Resistance of Fe-based Amorphous Coatings Pre- pared by Thermal Spraying JIANG Chao-ping, LIU Wang-qiang (School of Material Science and Engineering, Changan University, Xian 710064, China) ABSTRACT: Owing to excellent comprehensive performance, especially incomparable advantage in wear and corrosion resis- tance compared with traditional crystalline materials, thermal sprayed Fe-based amorphous coating is widely used for surface protection. However, as a typical lamellar structure, it has certain amount of pores inside as well, resulting in reduction of its corrosion resistance. Corrosion mechanism of Fe-based amorphous coating and factors influencing its corrosion resistance were first introduced, forming mechanism, classification and influencing factors of thermal sprayed Fe-based amorphous coating were summarized. Then research progress of relationship between pore defe