铝盐和铁盐对腐殖酸混凝特性的比较.pdfVIP

净水技术2008，27(1)：16—19 Water Purification Technol 铝盐和铁盐对腐殖酸混凝特性的比较 万俊力 ，王晓昌 ，金鹏康 (1．长沙理工大学水利学院，湖南长沙 410076，2、西安建筑科技大学，陕西西安 710055) 摘 要 以TOC和UV 为指标，比较了不同条件下铝盐和铁盐对腐殖酸的混凝效果。PDA在线监测结果表明，弱酸性条件下， 铁盐混凝稳定性优于铝盐。HPLC分析结果表明，混凝可以有效地去除分子量大于 1000的物质，且铁盐对大分子物质的去除更 彻底。GC—MS分析结果表明，腐殖酸是以羧基和羟基为其主要官能团的苯环或多环类复杂大分子有机物，在弱酸性条件下，铁 盐混凝对羧基类有机物的去除效果优于铝盐。但在pH为7．0的中性条件下，部分羟基和胺基类有机物不能被去除。 关键词 腐殖酸 铝盐 铁盐 混凝 中图分类号：TU528 文献标识码：B 文章编号：1009—0177(2008)01—0016一o4 Comparison of the Properties of Coagulation between Alum Sulfate and Ferric Chloride with Humic Acids WAN jan～li，WANG Xiao．chang ，JIN Peng．kang f1．Changsha University of Science＆Technology，Changsha 410076,China； 2．Xi’an University of A rchitect and Tech．，Xi’an 710055，China) Abstract Jar tests were conducted respectively for the coagulation of humic acids fHA)with alum SUifate and ferric chloride as coagulants at different pH values．The removal of HA，coagulation process，molecular weight(MW)distribution and functional groups of HA were studied by TOC，UV ，a photometric dispersion analyzer fPDA 2000)，HPLC and GC—MS techniques．Combining the removal of TOC and UV with online monitoring of PDA 2000， it could be concluded that at pH 5．0 ferric chloride had higher removal of HA than that of alum sulfate、HPLC analysis results showed that HA with MW higher than 1000Da could be removed more effectively when coagulant was ferric chloride． GC—MS analysis revealed that almost all organic matters with carboxyl and hydroxyl groups could be removed by coagulation at pH 5．0 and ferric chloride had higher removal than alum sulfate，while at pH 7．0， many hydroxyl and amidocyanogen groups could not be removed． Key words humic acids alum sulfate ferric chloride coagulation 为了去除水中天然有机物以达到控制消毒副产 溶于去离子水中，配成所需浓度的水样。提取腐殖酸 物的目的，强化混凝仍是首选处理方法『l_。自然水体 在碱性条件下经0．45 Ixm微孔滤膜过滤，以保证所 中天然有机物的主要代表为腐殖酸类物质，本文以 研究的对象为溶解