二元液态合金体系组元活度的热力学一致性检验-昆明理工大学学报.PDFVIP

33 3 ( ) V ol 33 N o3 2008 6 Journal ofK unm ing U n iversity of Sc ience and T echnology ( Sc ience and T echnology) Jun 2008 王 嵩, 陶东平, 杨红卫 ( , 650093) : 根据所查文献中大量液态合金组元活度的实验数据, 采用科学计算软件及方 , 获取了这 些数据的拟合曲线, 并应用 G ibb s- Duhem 方程的 函数 对 30 个二元液态合金体系组元活度 数据进行检验; 计算出二元系组元的活度值, 与实验值进行比较, 得出了 30 个二元液态合金体系 两组元的总平均相对误差分别为 160% 和 170% , 并补充了 12 个体系的无限稀活度系数; 表明 应用 G ibb s- Duhem 方程的 函数 可以很好的检验实验数据的热力学 一致性, 并准确地计算 出组元的无限稀活度系数 : 函数 ; 液态合金; 热力学; 冶金熔体 : TF6 1 : A : 1007- 855X ( 2008) 03- 0015 - 05 V erificat ion of T herm odynam ic C on sistency of Com ponent A ct iv ity D ata of B inary L iqu id A lloy s W ANG Song, TAO Dongp ing, YANG H ongw ei ( F acu lty of M a teria ls and M eta llurg ica l Eng ineer ing, Kunm ing U n iversity o f Sc ience and T echno logy, K unm ing 65009 3, Ch ina) Abs tract: Based on o f a large qu ant ity o f exp ermi ental data on liqu id alloy e lem ent activity from the literature, the fitt ing curve is ob tained w ith the adoption o f scientific m ethods and calcu lation softw are T he com ponent ac t iv ity data o f 30 b inary liqu id a lloys are verified by the - funct ion w hich is the conversion of G idds- Duhem e quat ion Through the com parison bewt een ca lculated va lu es and the exp er mi enta l data, it is found ou t that the average relat ive errors of the two com ponents are 160% and 170% resp ect ive ly Furtherm ore, the in fin ite d i lute activ ity coefficients of 12 b inary liqu id a lloys are suggested It is indicated through the results th at the m eth od is su itable to verify the therm odynam ic con sistency of expermi ent data, and to calcu la te the in