PMMA和PS对聚乙二醇结晶行为的影响.doc

本科毕业设计(论文) 题目：PMMA和PS对聚乙二醇结晶行为的影响 院 （系）： 材料与化工学院 专 业： 高分子材料与工程 班 级： 090307 学 生： 王康 学 号： 090307115 指导教师： 罗春燕 2013年 06月 PMMA和PS对聚乙二醇结晶行为的影响 摘要 结晶性聚合物的结晶过程是在加工成形过程中结构演变的主要过程之一，是决定最终聚集态结构和制品性能的关键因素。两种及以上的聚合物进行共混的方法常用来制备在某些性能上有所改进或具有独特性能的聚合物材料。 本采用本体聚合法合成不同分子量的聚甲基丙烯酸甲酯(PMMA)和聚苯乙烯(PS)，然后利用溶液共混的方法得到PMMA/PEG和PS/PEG共混物，再利用偏光显微镜、X射线衍射仪（XRD）、差示扫描量热仪（DSC）等手段表征共混物的结晶行为。结果表明，对于相容性的PMMA/PEG共混物，PMMA的加入量越多、分子量越大，导致PEG的结晶能力越差；不相容的PS/PEG共混物，PS的加入量越多、分子量越大，导致PEG的结晶能力越差。 而且PMMA对PEG结晶行为的影响明显强于PS对PEG结晶行为的影响。 关键词：本体聚合；共混物；相容；不相容；结晶行为 The effect of PMMA and PS on the crystallization of PEG Abstract The crystallization behavior of polymer is one of the main processes of formation evolution. It’s the key factor that determines the final state of aggregation and the nature of product. The blending method of two or more kinds of polymers is used to synthesize polymer material that with special property or further improved nature. The mass polymerization method was used to synthesize poly(methyl methacrylate) （PMMA ）and polystyrene (PS) with different molecular weights. Then the PMMA/PEG and PS/PEG blends can be obtained by solution blending. Finally the polarizing microscope, X-ray diffraction (XRD) and differential scanning calorimetry (DSC) method were used to characterize the crystallization behavior of blends. The results indicate that in miscible PMMA/PEG blends, the more PMMA or the larger molecular weight of PMMA were added, the more obvious effects on the crystallization behavior of PEG can be obversed. When the immiscible PS and PEG are mixed, the more PS are added, the larger molecular weight would be and the more clearly impact on the crystallization of PEG. Compared the impact of PMMA and PS on PEG crystallization, PMMA has much stronger impact on PEG crystallization than that of PS. Key words: mass polymerization; blends; miscible; immiscible; crystallization behavior 目录 摘要 I Abstract II 1 绪论