2种方法提取柑橘皮中挥发性成分的气质联用分析.pdfVIP

安徽农业科学，Journal of Anhui Agri. Sci. 2013 ,41 (3) : 1283 -1285 责任编霸李菲菲责任枝对况玲玲 2 种方法提取柑槽皮中挥发性成分的气质联用分析 辞成虎，王瑞斌 (榆林学院化学与化工学院，陕西榆林 719000) 摘要 [目的]分析比较不同方法提取柑椅皮中挥发性成分的效采。[方法]分别采用水蒸气蒸饱(50) 和超声萃取-水蒸气蒸饱 (UE50) 从柑椅皮中提取挥发油，通过气相色谱-质谱(GC-MS) 联用技术，比较分析了挥发油的化学成分;峰面积归一化法确定了各组 分的相对百分含量。[结果]50 法共分离出 30 个色谱峰，鉴定出 21 种物质，占总峰面积的 93.89% ，主要是邻苯二甲酸(51. 93%); UESO 法共分离出 45 个色谱峰，鉴定出 38 种物质，占总峰面积的 98.07% ，主要是 0-主烯(25.90% )等。[结论]2 种方法提取柑桶皮中 挥发油主要共有成分为有机戴和统短类化合物，但组成和含量有差异，SD 法提取有机酸的含量较高。 关键词柑桶皮;挥发油;GC-M5; 水蒸气蒸惚;超声萃取-水蒸气蒸饱 中图分类号 St崩 文献标i只码 A 文章编号 0517 -6611(2013)03 -01283 -03 Comparing Two KiI曲。IfMeth创Is ror Extraction of Vola甜.e Oils rrom Orange Peel and Com归nents A皿lysis by GC-MS XUE Cheng-hu et al ( Scb回1 of Chemistry and Chemical Engineering , Yulin University , Yulin , 5haanxi 719αlQ) Abstract [ Obj础ve 1To compare different extraction method for volatile oil from orange peel. [Method] The volatile oils were extracted from orange peel by steam distillation (50) and ultrasound -assisted s阳m distillation (UE50) , respectively. 亚le chemical constituents in 由e volatile oils were identified by G脑 Cbromatography-Mass Spectrome町 GC-MS and their relative contents were calculated b描ed on GC peak ar- eas. [Result] For 阳明1 distillation , 21 compounds of 30 detected pe如were identified , accounting for 93. 89% of the volatile fraction. The main compone瞄were dimethyl ph出血te( 5 1.93% ) ; For ultrasound-as田sted steam distillation , 38 compounds of 45 detected peaks were i- dentified , accounting for 98. 07% of the volatile fraction. The main componen恒 were 0-Limonene. [Conclusion] The results indicated 血剑， there is a significant difference in the composition and relative amounts between the volatile oils ohtained by SO and UESO methods; 由e com- mon components of the two extracts were organic acids and alkanes. SD method allows higher amount of organic acids than UESD. Key