Ta-TM(TM=Ti,Cr,Co,Ni)二元合金形成焓的亚规则模型.pdfVIP

Vo1.31. No.3 24 第31 卷第3 期 上海金属 2009 年 5 月 SHANGHAI METALS May.2009 丁和丁M(丁M = Ti , Cr , Co , Ni} 二冗合金形成始的亚规则模型 张淳1.2 廓树帜3 陈健s 费3 好旦在3 白云舆3 3:.小阳3 端端s 张邦维1 王玲玲1 (1.湖南大学庇用物闻系，长沙 41∞82; 2. 湖南师很大学数学与计算机科学学院; 3. 低飨镶子结构与调控教育部建点实骏案，湖南师范大学物理盟系) {摘要] 形成始是描述合会形成能力和稳定性的重要参数o .m.:æ.规则模型对 Ta斗W (TM =Ti , Cr , Co , Ni) 二元合金的形成始进行理论计算，目的是了解这四种 Ta 合会的热力 学性质，预圳其中间相的存在。结果显示亚规则棋型对所研究的二元合金的形成;除结果能准 确地描述和解释已有实栓结果。选为制备和开发广泛应用于化学工业的耐腐饿、航空航天工 业的高温结构 Ta 合金材料提供了理论支撑。 [关键诩} 担基二元.合金 形成始 .:æ.规则模型 SUBREGULAR MODEL FOR FORMATION ENTHALPY OF Ta-TM (TM 窍 Ti ， Cr , Co , Ni) BINARY ALLOYS Zhang Chun ,.2 Liao Shuzhe Chen Jia3 Peng Haojun3 Lu Yunbin3 Wang Xiaole Xie Bin3 Zhang Bangwei Wang Lingling ( 1. Department of Applied Physics , Hunan University; 2. College of MathematÎcs and Computer Science , Hunan Normal University; 3. Key Laboratory of 1ρw Dimensional Quantum Structures and Quantum Control of Ministry of Education , Hunan Normal University) Abstract] Formation enthalpy is an important parameter for the description of the formation and stability of the intermediate ph幽e. In order to know the thermodynamic prope时， the forming abilíty and stability of the íntermediate phase of the Ta based binary alloy , the subregular model was used to calculate the formalion enthalpy of Ta-TM (TM 昂啊， Cr , Co , Ni) binary alloys. 臼le experimental data available were compared WÍ由 the calculating results and found that there w制 agωd matching among the calculating results wÍth the experimental results.