静电纺丝技术制备TiO2@SiO2亚微米同轴电缆与表征Preparation.PDF

2007 年第65 卷 化 学 学 报 Vol. 65, 2007 第23 期, 2675～2679 ACTA CHIMICA SINICA No. 23, 2675～2679 ·研究论文· 静电纺丝技术制备 TiO @SiO 亚微米同轴电缆与表征 2 2 张双虎 董相廷* 徐淑芝 王进贤 (长春理工大学化学与环境工程学院 长春 130022) 摘要 用静电纺丝技术成功制备出大量的TiO ＠SiO 亚微米同轴电缆. 用TGA-DTA, XRD, SEM, TEM, EDS, FTIR 分 2 2 析技术对样品结构和组成进行了系统的表征. 结果表明, 得到的产物为 TiO2＠SiO2 亚微米级同轴电缆, 以无定型SiO2 为壳层, 晶态TiO2 为芯层, 电缆平均直径450 nm, 壳层厚度90 nm, 电缆长度＞300 μm, 同时在样品中发现个别纤维呈 现管状结构, 对其形成机理进行了讨论. 关键词 静电纺丝; 亚微米电缆; 同轴电缆; 二氧化钛; 二氧化硅 Preparation and Characterization of TiO ＠SiO Submicron-scaled 2 2 Coaxial Cables via a Static Electricity Spinning Technique ZHANG, Shuang-Hu DONG, Xiang-Ting* XU, Shu-Zhi WANG, Jin-Xian (School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022) Abstract Highly-yielded TiO ＠SiO submicron-scaled coaxial cables have been successfully synthesized 2 2 via a static electricity spinning technology. The microstructures and components of the samples were studied by TGA-DTA, XRD, SEM, TEM, EDS and FTIR techniques. The as-prepared sub-micro coaxial cables with a mean diameter of 450 nm and shell thickness of 90 nm had a crystalline TiO2 core and an amorphous shell of SiO . The length of the TiO ＠SiO cable was longer than 300 μm. Some submicron tubes were also 2 2 2 found in the samples, and their forma