固体酸方法降解纤维素.ppt

一.纤维素降解为葡萄糖 二.葡萄糖降解为HMF 目 录 Nature,2005,438(10),178 Angew. Chem. Int. Ed. 2004, 43, 2955 –2958 J. AM. CHEM. SOC. 2008,130(38),12787-12793 Chem. Mater. 2006, 18, 3039 3045 Green Chem., 2008, 10, 1033–1037 Selectivity=90%, yield=40.5% Chem. Commun., 2010, 46, 6935–6937 In addition, the mesoporous structure also facilitates the transportation of large molecules (such as glucose, cellobiose, cellotriose) in comparison with microporous carbons AC-N-SO3H-250 150 ℃,24h cellulose glucose Cov=74.3%, yield=61% cellulose glucose Cov=94.4%, yield=74.5% CMK-3 150 ℃,24h cellulose glucose yield=16