加州大学伯克利分校有机化学课件79548.pptVIP

? Univesity of California Chapter 14 Delocalized Pi Systems 2-Propenyl (Allyl) Clearly: Allylic · are stabilized. MO Picture of 2-Propenyl (Allyl) Interactions of a singly occupied p-orbital with each of the π molecular orbitals Reactivity of Allylic Position D. Allylic Organometallics Conjugated Double Bonds Structure Orbitals NMR Kinetic vs Thermodynamic Control Extended Conjugation Cyclohexatriene is Special - Benzene Extended Conjugation in Natural and Unnatural Products Organic Conductors Conjugated Systems Undergo Special Transformations: Pericyclic Reactions The Diels-Alder Reaction i