加州大学伯克利分校有机化学课件79573.pptVIP

? Univesity of California Structure of Double Bond How Weak is the ? Bond? Bond Strengths (kcal/mol) Acidity: Coupling Constants Vibrations in Molecules: Infrared (IR) Spectroscopy Infrared Modes The Infrared Spectrometer Degrees of Unsaturation Relative Stability of Alkenes Synthesis of Alkenes Acid-Mediated Dehydration of Alcohols Dehydration with Rearrangement Most useful: υC H ~ - 1. Alkyl = 2900cm-1 υCsp2 H ~ - = 3080 cm-1, υC C ~ - - = 1640 cm-1, C C H R R H trans υ = 970 cm-1 ~ R O H 2. Alkenes 3. H H Trans-2-hexene 4. O C 1740 cm-1 3350 cm-1 (broad) Molecular formula te