聚乙烯醇硫酸钾的合成及表征.docVIP

本科毕业论文 PVSK阳离子滴定剂的合成与表征 姓 名 范峥豪 学 院 理学院 专 业 应用化学 指导教师 田振然 讲师 完成日期 2012年6月  上海理工大学 全日制本科生毕业设计（论文）承诺书 本人郑重承诺：所呈交的毕业设计（论文） 是在导师的指导下，严格按照学校和学院的有关规定由本人独立完成。文中所引用的观点和参考资料均已标注并加以注释。论文研究过程中不存在抄袭他人研究成果和伪造相关数据等行为。如若出现任何侵犯他人知识产权等问题，本人愿意承担相关法律责任。 承诺人（签名）： 日 期： 聚乙烯醇硫酸钾的合成及表征 摘 要 聚乙烯硫酸钾Polyvinyl Sulfate Potassium）简称PVSK无色、略带微黄褐色的可与水及乙醇以任意比例混合(PVSK) 是胶体滴定技术中应用的标准阴离子聚合电解质。经常用于阳离子或碱性高分子的定量PVSK 的方法和制备过程中的影响因素。以氯代十六烷基吡啶为基准物、BaCl2为指示剂测定了PVSK 溶液中阴离子的浓度以及PVSK 的酯化度。以酯化度97. 7%的PVSK 为标准物，PVSK进行了表征。用浓硫酸作为磺化剂自制PVSK 的酯化度最高为80.5%，;  Synthesis and Characterization of Polyvinyl Sulfate Potassium ABSTRACT Polyvinyl alcohol, potassium sulfate (Polyvinyl sulfate Potassium) referred PVSK, colorless, slightly micro-tan solid, mixed with water and ethanol in any proportion. Polyvinyl alcohol potassium sulfate (PVSK) is a standard anionic polyelectrolyte colloid titration technique applied. Often used for quantitative analysis of the cation or alkaline polymer, widely used in papermaking and food industries. This article discusses the use of polyvinyl alcohol, pyridine, potassium hydroxide and concentrated sulfuric acid for the synthesis of PVSK the process. Factors affecting the method and preparation of different polyvinyl alcohol, pyridine, sulfuric acid, the ratio of raw materials preparation PVSK. Cetylpyridinium Chloride in the base material, the BaCl2 measured as the indicator anion concentration in the PVSK solution and PVSK the degree of esterification. Degree of esterification 97.7% of PVSK standard material, the use of infrared spectroscopy to the qualitative research on the products obtained were characterized using infrared spectroscopy on the synthesis of the high degree of esterification PVSK. Concentrated sulfuric acid as sulfonating agent homemade PVSK the highest degree of esterification of 80.5%, reaching the requirements of the colloid titration. KEYWORDS：Polyvinyl