一多相混输管道水合物生成及其浆液输送-中国石油大学学报.PDF

2013年摇 第37卷摇 摇 摇 摇 摇 摇 中国石油大学学报(自然科学版)摇 摇 摇 摇 摇 摇 摇 摇 Vol.37摇 No.5 摇 第5期摇 摇 摇 摇 摇 摇 摇 摇 Journal of China University of Petroleum摇 摇 摇 摇 摇 摇 摇 摇 Oct.2013 摇 摇 文章编号:1673鄄5005(2013)05鄄0163鄄05摇 摇 摇 doi:10.3969/ j.issn.1673鄄5005.2013.05.023 一多相混输管道水合物生成及其浆液输送 宫摇 敬,史博会, 吕晓方 (中国石油大学油气管道输送安全国家工程实验室,北京 102249) 摘要:根据经典的理论研究,依托良好的实验条件,对多相混输管道水合物生成及其浆液输送规律进行研究。 结果 表明:综合结晶本征动力学传热与传质所建立的水合物壳双向生长模型能有效预测油水乳状液下水合物生成过程 中的气体消耗量;在高压水合物生成实验环道上,借助 FBRM (颗粒粒度分析仪)和PVM (颗粒录影显微仪)设备可 探究水合物生成过程中颗粒/ 液滴的分布规律;考虑到多相混输管道水合物浆液的输送安全性,流动须满足“最低安 全流量冶的要求;在高压水合物生成实验环道上,可直观研究不同含水率下天然气-水合物浆液的流型特点。 关键词:天然气水合物;生成动力学模型;多相流动;浆液输送;流型 中图分类号:TE832摇 摇 摇 文献标志码:A Gas hydrate formation and hydrate slurry flow in multiphase transportation system GONGJing,SHI Bo鄄hui,L譈 Xiao鄄fang (College of Mechanical and Transportation Engineering in China University of Petroleum,Beijing 102249,China) Abstract:Using classic theories and experimental approaches,gas hydrate formation and hydrate slurry flow in multiphase transportation system were investigated. An inward and outward hydrate growth shell model was developed,taking into con鄄 siderationoftheintrinsickinetics,massandheattransfer,whichcouldaccuratelypredicttheamountof gasconsumedduring the hydrateformation process. With FBRM and PVM installed,the distribution of the hydrate particles can be observed in high pressure hydrateslurryflowloop. Forthesafetyof hydrateslurryflow inmultiphasetransportationsystem,itisnecessa鄄 ry for flowtomeetthe minimumsafetyflowrate requirement. Thecharacteristicsof gas鄄hydrateslurryflowpatternscanbe efficiently investigated by experiments carried out in the high pressure hydrate slurry flow loop. Key words:natural gas hydrates;kineticsformation model;multiphaseflow;slurry transportation;f