交联壳聚糖富集-原子吸收光谱法测定食品工业用水中痕量镉.PDF

※分析检测 食品科学 2009, Vol. 30, No. 16 231 王和才 (苏州农业职业技术学院食品系，江苏苏州 215008) 研究环氧氯丙烷交联制得的交联壳聚糖对水中痕量Cd2+ 的吸附行为。用正交试验筛选确定影响吸附性能最 明显的因素是溶液pH 值，其次是交联壳聚糖用量。优化因素水平下该方法进行分离富集测定，Cd2+ 去除率平均 值为97.4% ，RSD=8.4%(n=6) ，平均饱和吸附容量为45.6mg/g ，精密度良好。交联壳聚糖分离富集用于食品工业 用水中痕量镉的测定时间快、效果好、操作简单，回收率可达到97.2% ～103.3% 。 交联壳聚糖；分离富集；镉离子；正交试验；原子吸收光谱法 Adsorption of Cadmium onto Cross-linked Chitosan and Its Application in Atomic Absorption Spectrometric Determination of Trace Cadmium in Food Industrial Water WANG He-cai (Department of Food, Suzhou Polytechnic Institute of Agriculture, Suzhou 215008, China) Abstract：The adsorption behavior of cross-linked chitosan prepared with epichlorohydrin to trace cadmium ( Ⅱ) in water was investigated. One-factor-at-a-time and orthogonal array methods were applied to maximize adsorption of cross-linked chitosan to cadmium. Range analysis proved that the most significant factor affecting adsorption was pH of solution, followed by amount of added cross-linked chitosan. The average removal rate of Cd2+ was 97.4% with a RSD of 8.4% (n = 6) and the average saturated absorption capacity was 45.6 mg/g, suggesting good precision. The enrichment of cadmium with cross-linked chitosan was applied to the atomic absorption spectrometric determination of trace cadmium in brewery industrial water. This method is fast, effective and simple for the determination of trace cadmium in food industrial water with a high recovery of 97.2%－103.3%. Key words：cross-linked chitosan；separation and enrichment；cadmium；orthogonal array design；atomic absorption spectrometry 中图分类号：TS207.51 文献标识码：A 文章编号：1002-6630(2009)16-0231-04 镉是金属元素中对人体