液晶性树状高分子Core.PDFVIP

第 17 卷 第 5 期 化 　学 　进 　展 Vol . 17 No . 5 2005 年 9 月 PROGRESS IN CHEMISTRY 　Sep . , 2005 液晶性树状高分子 赵雅青 　董炎明 　李 　　 　黄剑莹 　郑钦健 　陈小君 ( 厦门大学材料科学与工程系 　厦门 361005) 摘 　要 　对树状高分子进行功能化 ,使之成为具有特定性能的新型材料是 目前很热门的课题 ,树状液晶 就是其中之一 。树状高分子长径比很小 ,似乎难以形成液晶态 ,但人们已发现多种树状液晶分子 ,几乎囊括 了所有在其他高分子中出现过的液晶相 。本文按液晶相分类 ,介绍树状液晶高分子的研究进展 。 关键词 　树枝状高分子 　超支化高分子 　液晶 + ( ) 中图分类号 : O6311 ; O753 2 　文献标识码 : A 　文章编号 : 1005281X 2005 Liquid Crystal Dendritic Polymers Zhao Yaqing 　Dong Yanming 　L i J un 　Huang J iany ing 　Zheng Qinj ian 　Chen X iaoj un (Department of Materials Science and Engineering , Xiamen University , Xiamen 361005 , China) Abstract 　Dendritic polymers including dendrimers and hyperbranched polymers are novel class of synthesized polymers. They have received more and more research interest from materials scientists because of their unique structure characteristics and applications. They are functionalized to given properties , such as liquid crystallinity according to the small length to diameter ratio . Dendrimers display a treelike architecture and are not expected to display liquid crystallinity. But several research group s focused on the selforganization of dendrimers and hyperbranched polymers in liquid crystalline phase and reported many types of liquid crystals , which covered almost all the liquid crystalline phase reported in other polymers. The recent advance in liquid crystal dendritic polymer based on the different types of liquid crystal phases is reviewed in this paper . Key words 　dendrimers ; hyperbranched polymers ; liquid