a new approach for the modification of paper surface properties using polyoxometalates新方法使用金属纸表面属性的修改.pdfVIP
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a new approach for the modification of paper surface properties using polyoxometalates新方法使用金属纸表面属性的修改
Materials 2010, 3, 201-215; doi:10.3390/ma3010201
OPEN ACCESS
materials
ISSN 1996-1944
/journal/materials
Article
A New Approach for the Modification of Paper Surface
Properties Using Polyoxometalates
Mikhail S. Saraiva 1, José A. F. Gamelas 1,*, António P. Mendes de Sousa 2, Bruno M. Reis 2,
José L. Amaral 2 and Paulo J. Ferreira 1,*
1 Departamento de Engenharia Química, Universidade de Coimbra, Pólo II – R. Sílvio Lima,
3030-790 Coimbra, Portugal; E-Mail: mikhasa@ (M.S.S.)
2 RAIZ – Instituto de Investigação da Floresta e Papel, Quinta de São Francisco, Apartado 15,
3801-501 Eixo, Portugal; E-Mails: mendes.sousa@ (A.P.M.d.S.);
reisbruno24@ (B.M.R.); jose.luis.amaral@ (J.L.A.)
* Authors to whom correspondence should be addressed; E-Mails: jafgas@eq.uc.pt (J.A.F.G.);
paulo@eq.uc.pt (P.J.F.); Tel.: +351 239798740 (J.A.F.G.); +351 239798747 (P.J.F.);
Fax: +351 239798703 (J.A.F.G.); +351 239798703 (P.J.F.).
Received: 3 November 2009; in revised form: 28 December 2009 / Accepted: 4 January 2010 /
Published: 7 January 2010
Abstract: A new approach for the chemical modification of the surface of paper based on
the application of colloidal mixtures containing cationic starch and polyoxometalates on
uncoated base paper is presented. Polyoxometalates with the Keggin-type structure and
physical properties similar to those presented by coating pigments, namely
H PW O ·23H O, H SiW O ·24H O, and K PW O ·9H O, have been used in order
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