a one-dimensional coordination polymer constructed from cadmium(ii) cations and sparfloxacinate anions一维配位聚合物由镉(二)阳离子和sparfloxacinate阴离子.pdfVIP

下载本文档

6
0
约2.47万字
约 8页
2017-09-07 发布于上海
举报
版权申诉

a one-dimensional coordination polymer constructed from cadmium(ii) cations and sparfloxacinate anions一维配位聚合物由镉(二)阳离子和sparfloxacinate阴离子.pdf

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

a one-dimensional coordination polymer constructed from cadmium(ii) cations and sparfloxacinate anions一维配位聚合物由镉(二)阳离子和sparfloxacinate阴离子

Crystals 2012, 2, 1366-1373; doi:10.3390/cryst2041366 OPEN ACCESS crystals ISSN 2073-4352 /journal/crystals Short Note A One-Dimensional Coordination Polymer Constructed from Cadmium(II) Cations and Sparfloxacinate Anions Zhe An 1, Jing Gao 2 and William T. A. Harrison 3,* 1 School of Chemistry and Life Science, Guangdong University of Petrochemical Technology, Maoming 525000, China; E-Mail: anzhe6409@ 2 Department of Pharmacy, Mudanjiang Medical University, Heilongjiang 157011, China; E-Mail: gaojing_mmu@163.com 3 Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, UK * Author to whom correspondence should be addressed; E-Mail: w.harrison@abdn.ac.uk; Tel.: +44-1224-272897; Fax: +44-1224-272921. Received: 28 June 2012; in revised form: 22 August 2012 / Accepted: 1 September 2012 / Published: 28 September 2012 Abstract: The synthesis and crystal structure of the one-dimensional coordination polymer, [Cd(spar) ] ·n(H O), are described, where spar− is the sparfloxacinate anion, 2 n 2 − 2+ − C H N O F . The Cd ion is bonded to four spar ligands: Two O,O-chelate with their 19 21 4 3 2 β-keto carboxylate groupings and two are monodentate-bound through a carboxylate O atom, to result in a distorted CdO6 octahedral coordination geometry. The bridging ligands lead to [100] polymeric chains in the crystal and N–H···O hydrogen