城市生活垃圾热解特性的TG_DSC分析_李季.pdfVIP

　53 　7 　　　　 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　V　ol.　5　3　№7 　　2002 7 　　　　　　　Journal　of 　Chemical　Industry 　and　Engineering　 (China)　　　 July　2002 TG-DSC　　　　 李　季 　张　铮 　杨学民　姚建中　林伟刚　　　　　 (, 100080)　　　　　　 　　　　　 　X 705 　　　　　　A 　　　　　　0 38-1157 (2002)07-0759-06 TG-DSC STUDY ON PYROLYSIS CHARACTERISTICS OF MUNICIPAL SOLID WASTES LI Ji, ZHANG Zheng, YANG Xuemin, YAO Jianzh ng and LIN Weigang (Multi-phase Reaction Laboratory, Institute of Process Engineering, Chinese Academy of Sciences, Beij ing 100080, China) Abstract 　Seven typical components in municipal solid w astes (MSWs)———paper, food, textile, wood, straw, plastic and rubber w ere chosen as the thermogravimetric analysis samples in this paper to study the pyrolysis characteristics.By the thermogravimetry and differential scanning calorimetry (TG-DSC )analysis, pyrolysis characteristics of M SWs components and pyrolysis endothermal enthalpy were obtained.The kinetic parameters of pyrolysis were determined with the Doyle method and a multi-stage first order pyrolysis model w as proposed.The simulated results by this model show ed good agreement w ith the TG experimental data. The pyrolysis characteristics provide significant parameters to a new concept of circulating fluidized bed incinerator, w hich can simultaneously restrain the high-temperature HCl corrosion and emission of dioxins. Keyw rds 　MSWs, thermogravimetry, differential scanning calorimetry, pyrolysis characteristics, kinetic parameters , 引　言 , [ 1～5] . 、 , , , , .2000 7 TG -DSC , 2000 MW, , 2010 000 MW, 2002 . 2 ～3 , 1　热分析方法 30MW. . 1.1　 1300 t SETRAM LAB- 8 , 1.36×10 kW ·h. SYS .-(TG - , DTA)-(TG-D