可见波段彩色结构色.pdf

Structural Color Films with Lotus Effects, Superhydrophilicity, and Tunable Stop-Bands OSAMU SATO,*,† SHOICHI KUBO,‡ AND ZHONG-ZE GU*,§ †Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka, 816-8580, Japan, ‡Chemical Resources Laboratory, Tokyo Institute of Technology, R1-11, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan, §State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China RECEIVED ON SEPTEMBER 7, 2007 C O N S P E C T U S he structural blue color of a Morpho butterfly originates from the diffraction of light and interference effects due to the pres- Tence of the microstructures on the wing of the butterfly. Structural color on the surface of a damselfish reversibly changes between green and blue. Inspired by these creatures, we have been trying to prepare high-quality and functional structural color films. We describe our efforts in this Account. A useful technique to prepare such structural color films in colloidal solution is a “lifting” method, which allows us to quickly fabricate brilliant colloidal crystal films. The thicknesses of the films can be controlled by precisely adjusting the particle concen- tration and the lifting speed. Moreover, in order to prepare a complicated structure, we have used template methods. Indeed, we have successfully prepared the inverse structure of the wing of a Morpho butterfly with this technique. Initially, however, our struc-